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Effect of organic modifiers on the capacity factor in micellar electrokinetic chromatography

文献类型：期刊论文

作者Shi, W; Zhang, J; Wang, L; Zou, HF; Zhang, YK
刊名CHINESE JOURNAL OF CHEMISTRY
出版日期1997
卷号15期号:2页码:144-153
关键词Micellar Electrokinetic Chromatography Organic Modifiers Capacity Factor Migration Time Window
ISSN号1001-604X
文献子类Article
英文摘要Organic modifiers were effective both to extend the migration time window and to improve the separation of very hydrophobic compounds in MEKC. An iteration method was used to determine the migration time of micelles. The quantitative relationship between the capacity factor k' and the concentration of organic modifiers was derived, which was investigated experimentally. The linear solvation energy relationships (LSER) methodology was applied to MEKC, and good linear relationships between lnk' and solvatochromic parameters of 15 solutes were obtained in the presence of organic modifier in different concentrations, which indicated a new access in MEKC to predict k' from the structural parameters of solutes. The effect of column temperature T on k' was also investigated.
WOS关键词SOLVATION ENERGY RELATIONSHIPS ; CAPILLARY
WOS研究方向Chemistry
语种英语
WOS记录号WOS:A1997XL35500008
出版者SCIENCE CHINA PRESS
源URL[http://cas-ir.dicp.ac.cn/handle/321008/168244]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Shi, W
推荐引用方式
GB/T 7714		 Shi, W,Zhang, J,Wang, L,et al. Effect of organic modifiers on the capacity factor in micellar electrokinetic chromatography[J]. CHINESE JOURNAL OF CHEMISTRY,1997,15(2):144-153.
APA Shi, W,Zhang, J,Wang, L,Zou, HF,&Zhang, YK.(1997).Effect of organic modifiers on the capacity factor in micellar electrokinetic chromatography.CHINESE JOURNAL OF CHEMISTRY,15(2),144-153.
MLA Shi, W,et al."Effect of organic modifiers on the capacity factor in micellar electrokinetic chromatography".CHINESE JOURNAL OF CHEMISTRY 15.2(1997):144-153.

入库方式： OAI收割

来源：大连化学物理研究所

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