A HREELS study of the adsorption of formic acid on slightly oxidized Nb(110) surface
文献类型：期刊论文
| 作者 | Wang, YS; Wei, XM; Tian, ZJ; Zhai, RS; Ushikubo, T; Sato, K; Zhuang, SX |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1997-02-01 |
| 卷号 | 40期号:1页码:9-14 |
| 关键词 | Adsorption Of Formic Acid Nb(110) Surface Hreels |
| ISSN号 | 1001-652X |
| 文献子类 | Article |
| 英文摘要 | An investigation has been made on the adsorption and decomposition of formic acid on slightly oxidized Nb(110) surface (O/Nb atom ratio = 0.2) using high resolution electron energy loss spectroscopy (HREELS), and a corresponding surface reaction mode is given. At 140 K, formic acid of low exposure on such an Nb(110) surface decomposed to formate, which bonded on Nb in monodentate configuration, simultaneously some formate decomposed to CO, which adsorbed on the surface. Formic acid multilayers formed when the exposure was high. While the temperature was increased to above 190 K, multilayer formic acid desorbed, and the surface was covered with monodentate-bonded formate and CO. In the temperature range of 250-300 K, chemisorbed formate changed from monodentate configuration into bridging configuration and CO molecules disappeared. The decomposition of formate at higher temperatures led to the oxidation of Nb. The formate formed in the high exposure case was so stable that it did not decompose even the temperature was as high as 540 K. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:A1997WJ36900002 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168292]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CHINESE ACAD SCI,DALIAN INST CHEM PHYS,STATE KEY LAB CATALYSIS,DALIAN 116023,PEOPLES R CHINA 2.MITSUBISHI CHEM CORP,YOKOHAMA,KANAGAWA,JAPAN 3.UNIV SCI & TECHNOL CHINA,DEPT CHEM PHYS,HEFEI 230026,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Wang, YS,Wei, XM,Tian, ZJ,et al. A HREELS study of the adsorption of formic acid on slightly oxidized Nb(110) surface[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1997,40(1):9-14. |
| APA | Wang, YS.,Wei, XM.,Tian, ZJ.,Zhai, RS.,Ushikubo, T.,...&Zhuang, SX.(1997).A HREELS study of the adsorption of formic acid on slightly oxidized Nb(110) surface.SCIENCE IN CHINA SERIES B-CHEMISTRY,40(1),9-14. |
| MLA | Wang, YS,et al."A HREELS study of the adsorption of formic acid on slightly oxidized Nb(110) surface".SCIENCE IN CHINA SERIES B-CHEMISTRY 40.1(1997):9-14. |
入库方式： OAI收割
来源：大连化学物理研究所
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