Asymmetric Total Synthesis of (-)-Clovan-2,9-dione Using Rh(I)-Catalyzed [3+2+1] Cycloaddition of 1-Yne-vinylcyclopropane and CO
文献类型：期刊论文
| 作者 | Yang, Jun; Xu, Wenbo; Cui, Qi; Fan, Xing; Wang, Lu-Ning; Yu, Zhi-Xiang |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-11-17 |
| 卷号 | 19期号:22页码:6040-6043 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b02656 |
| 文献子类 | Article |
| 英文摘要 | The asymmetric total synthesis of clovan-2,9-dione with a [6.3.1.0(1,5)]dodecane skeleton has been achieved. The synthesis features a Rh(I)-catalyzed [3 + 2 + 1] cycloaddition of 1-yne-vinylcyclopropane (1-yne-VCP) with CO and an intramolecular aldol reaction to obtain the skeleton of the target molecule. |
| WOS关键词 | STEREOSPECIFIC SYNTHESES ; CARYOPHYLLENE OXIDE ; FORMAL SYNTHESIS ; CLOVANE ; BIOTRANSFORMATION ; SESQUITERPENOIDS ; STEREOCHEMISTRY ; REARRANGEMENT ; DERIVATIVES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000416204300003 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168348]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhi-Xiang |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Jun,Xu, Wenbo,Cui, Qi,et al. Asymmetric Total Synthesis of (-)-Clovan-2,9-dione Using Rh(I)-Catalyzed [3+2+1] Cycloaddition of 1-Yne-vinylcyclopropane and CO[J]. ORGANIC LETTERS,2017,19(22):6040-6043. |
| APA | Yang, Jun,Xu, Wenbo,Cui, Qi,Fan, Xing,Wang, Lu-Ning,&Yu, Zhi-Xiang.(2017).Asymmetric Total Synthesis of (-)-Clovan-2,9-dione Using Rh(I)-Catalyzed [3+2+1] Cycloaddition of 1-Yne-vinylcyclopropane and CO.ORGANIC LETTERS,19(22),6040-6043. |
| MLA | Yang, Jun,et al."Asymmetric Total Synthesis of (-)-Clovan-2,9-dione Using Rh(I)-Catalyzed [3+2+1] Cycloaddition of 1-Yne-vinylcyclopropane and CO".ORGANIC LETTERS 19.22(2017):6040-6043. |
入库方式： OAI收割
来源：大连化学物理研究所
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