Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions
文献类型：期刊论文
| 作者 | Su, Xiong1; Yang, Xiaoli1,2; Zhao, Bo3; Huang, Yanqiang1 |
| 刊名 | JOURNAL OF ENERGY CHEMISTRY
 |
| 出版日期 | 2017-11-01 |
| 卷号 | 26期号:5页码:854-867 |
| ISSN号 | 2095-4956 |
| 关键词 | Rwgs Reaction Carbon Dioxide Hydrogenation Supported Metal Catalyst Metal Oxide Transition Metal Carbide |
| DOI | 10.1016/j.jechem.2017.07.006 |
| 文献子类 | Review |
| 英文摘要 | Reverse water gas shift (RWGS) reaction can be served as a pivotal stage of transitioning the abundant CO2 resource into chemicals or hydrocarbon fuels, which is attractive for the CO2 utilization and of eventually significance in enabling a rebuilt ecological system for unconventional fuels. This concept is appealing when the process is considered as a solution for the storage of renewable energy, which may also find a variety of potential end uses for the outer space exploration. However, a big challenge to this issue is the rational design of high temperature endurable RWGS catalysts with desirable CO product selectivity. In this work, we present a comprehensive overview of recent publications on this research topic, mainly focusing on the catalytic performance of RWGS reaction over three major kinds of heterogeneous catalysts, including supported metal catalysts, mixed oxide catalysts and transition metal carbides. The reaction thermodynamic analysis, kinetics and mechanisms are also described in detail. The present review attempts to provide a general guideline about the construction of well-performed heterogeneous catalysts for the RWGS reaction, as well as discussing the challenges and further prospects of this process. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| WOS关键词 | WATER-GAS-SHIFT ; CARBON-DIOXIDE HYDROGENATION ; MONODISPERSED NIO PARTICLES ; PROMOTED CU/SIO2 CATALYST ; SUPPORTED RH CATALYSTS ; SINGLE-ATOM CATALYSTS ; CO2 HYDROGENATION ; PT/TIO2 CATALYSTS ; PT/CEO2 CATALYST ; ENHANCED SELECTIVITY |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000415598900005 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168354]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Huang, Yanqiang |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Future Sci & Technol City, GEIRI, Renewable Energy Storage Div, Beijing 102211, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, Xiong,Yang, Xiaoli,Zhao, Bo,et al. Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(5):854-867. |
| APA | Su, Xiong,Yang, Xiaoli,Zhao, Bo,&Huang, Yanqiang.(2017).Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions.JOURNAL OF ENERGY CHEMISTRY,26(5),854-867. |
| MLA | Su, Xiong,et al."Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: recent advances and the future directions".JOURNAL OF ENERGY CHEMISTRY 26.5(2017):854-867. |
入库方式： OAI收割
来源：大连化学物理研究所
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