Syntheses, structure and properties of a new Fillowite-type compound Na0.48Mn1.22PO4
文献类型：期刊论文
| 作者 | Zhao, Pan1; Feng, Kai2; Wang, Yonggang3; Gao, Jianhua1,4 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2018-02-15 |
| 卷号 | 734页码:229-234 |
| 关键词 | Fillowite Single-crystal Structure Polyanionic Cathode |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2017.10.214 |
| 文献子类 | Article |
| 英文摘要 | Searching for excellent polyanionic cathode materials for Na-ion batteries attract considerable attention in recent years. Herein, a new polyanionic cathode candidate Na0.48Mn1.22PO4, crystallizing in the space group R-3 with the unit cell parameters of a = 15.3672 (17) angstrom, c = 43.503 (5) angstrom and V = 8896.91 (2) angstrom(3), belonging to the Fillowite-type structure, is reported for the first time. In the structure of Na0.48Mn1.22PO4, the Mn-O connectivity exhibits three-dimensional Mn-O-Mn network. More interestingly, some Mn5O6 clusters embed in the network. Electrochemical tests revealed that Na0.48Mn1.22PO4 can be very effectively cycled against a Na metal electrode with an average voltage of 3.35 V. In addition, The XANES and magnetic tests were also employed for the characterization of the material. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | SODIUM-ION BATTERIES ; ELECTROCHEMICAL PROPERTIES ; CRYSTAL-STRUCTURE ; RECHARGEABLE BATTERIES ; POSITIVE ELECTRODE ; CATHODE MATERIAL ; ALLUAUDITE-TYPE ; PHASE ; PHOSPHATE ; LITHIUM |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000418517100029 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168360]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Jianhua |
| 作者单位 | 1.Northwest Univ, Sch Phys, Dept Mat Phys, Xian 710069, Shaanxi, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 3.Carnegie Inst Sci, Geophys Lab, HPSynC, Argonne, IL USA 4.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Pan,Feng, Kai,Wang, Yonggang,et al. Syntheses, structure and properties of a new Fillowite-type compound Na0.48Mn1.22PO4[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,734:229-234. |
| APA | Zhao, Pan,Feng, Kai,Wang, Yonggang,&Gao, Jianhua.(2018).Syntheses, structure and properties of a new Fillowite-type compound Na0.48Mn1.22PO4.JOURNAL OF ALLOYS AND COMPOUNDS,734,229-234. |
| MLA | Zhao, Pan,et al."Syntheses, structure and properties of a new Fillowite-type compound Na0.48Mn1.22PO4".JOURNAL OF ALLOYS AND COMPOUNDS 734(2018):229-234. |
入库方式： OAI收割
来源：大连化学物理研究所
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