Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P-3 Complexes
文献类型：期刊论文
| 作者 | Du, Shanshan1; Yin, Jianhao1; Chi, Yue1; Xu, Ling1; Zhang, Wen-Xiong1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-12-11 |
| 卷号 | 56期号:50页码:15886-15890 |
| ISSN号 | 1433-7851 |
| 关键词 | Metallacycles P-4 Functionalization Phospholyl Lithium Phosphorus Complexes Rare-earth Elements |
| DOI | 10.1002/anie.201708897 |
| 文献子类 | Article |
| 英文摘要 | The [3+1] fragmentation reaction of rare-earth metallacyclopentadienes 1a-c with 0.5equivalents of P-4 affords a series of rare-earth metal cyclo-P-3 complexes 2a-c and a phospholyl anion 3. 2a-c demonstrate an unusual (3) coordination mode with one P-P bond featuring partial -bonding character. 2a-c are the first cyclo-P-3 complexes of rare-earth metals, and also the first organo-substituted polyphosphides in the category of Group3 and f-block elements. Rare-earth metallacyclopentadienes play a dual role in the combination of aromatization and Diels-Alder reaction. Compounds 2a-c can coordinate to one or two [W(CO)(5)] units, yielding 4a-c or 5c, respectively. Furthermore, oxidation of 2a with p-benzoquinone produces its corresponding phospholyllithium and regenerated P-4. |
| WOS关键词 | P BOND FORMATION ; P-4 ACTIVATION ; TERMINAL PHOSPHIDE ; LIGAND ; TRANSFORMATION ; MECHANISM ; ELEMENTS ; BEHAVIOR ; LITHIUM ; COBALT |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000417200600013 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168402]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Shanshan,Yin, Jianhao,Chi, Yue,et al. Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P-3 Complexes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(50):15886-15890. |
| APA | Du, Shanshan,Yin, Jianhao,Chi, Yue,Xu, Ling,&Zhang, Wen-Xiong.(2017).Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P-3 Complexes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(50),15886-15890. |
| MLA | Du, Shanshan,et al."Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P-3 Complexes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.50(2017):15886-15890. |
入库方式： OAI收割
来源：大连化学物理研究所
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