tert-Butylation of naphthalene by tertiary butanol over HY zeolite and cerium-modified HY catalysts
文献类型：期刊论文
| 作者 | Huang, Zhihua1,2; Zhang, Jie1,2; Li, Peidong1,2; Xu, Lanjian1,2; Zhang, Xiaomin1; Yuan, Yangyang1; Xu, Lei1 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2017-10-21 |
| 卷号 | 7期号:20页码:4700-4709 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c7cy01227f |
| 文献子类 | Article |
| 英文摘要 | tert-Butylation of naphthalene is a promising process for the production of 2,6-DANs, which are fundamental starting materials for PEN. Herein, the tert-butylation of naphthalene with tertiary butanol was carried out in the liquid phase over a series of Ce-modified HY zeolites. XRD, SEM, TEM, XPS, NH3-TPD and FT-IR characterization studies proved that the Ce species dispersed uniformly on the HY zeolite in the form of small cerium oxide clusters/ nanoparticles. The formed Ce2O3 and CeO2 interacted with the hydroxyl groups in the zeolite, which caused the passivation of silicon-aluminium bridge hydroxyl groups in supercages and sodalite cages, resulting in the decrease of acid concentration and acid strength. Due to the weakened acid strength, the selectivity for 2,6-DTBN in the pores was greatly enhanced. Moreover, the non-selective acid sites on the external surface were reduced by Ce modification, which effectively inhibited dealkylation and isomerization reactions and thus helped to maintain the high selectivity for 2,6-DTBN. |
| WOS关键词 | SHAPE-SELECTIVE SYNTHESIS ; EXTERNAL ACID SITES ; LARGE-PORE ZEOLITES ; MOLECULAR-SIEVE CATALYSTS ; MORDENITE CATALYSTS ; REGIOSELECTIVE DIALKYLATION ; CO ADSORPTION ; LIGHT OLEFINS ; Y-ZEOLITES ; ISOPROPYLATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000413192900014 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168412]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yuan, Yangyang; Xu, Lei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Zhihua,Zhang, Jie,Li, Peidong,et al. tert-Butylation of naphthalene by tertiary butanol over HY zeolite and cerium-modified HY catalysts[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(20):4700-4709. |
| APA | Huang, Zhihua.,Zhang, Jie.,Li, Peidong.,Xu, Lanjian.,Zhang, Xiaomin.,...&Xu, Lei.(2017).tert-Butylation of naphthalene by tertiary butanol over HY zeolite and cerium-modified HY catalysts.CATALYSIS SCIENCE & TECHNOLOGY,7(20),4700-4709. |
| MLA | Huang, Zhihua,et al."tert-Butylation of naphthalene by tertiary butanol over HY zeolite and cerium-modified HY catalysts".CATALYSIS SCIENCE & TECHNOLOGY 7.20(2017):4700-4709. |
入库方式： OAI收割
来源：大连化学物理研究所
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