Gas-permeation performance of metal organic framework/polyimide mixed-matrix membranes and additional explanation from the particle size angle
文献类型：期刊论文
| 作者 | Duan, Cuijia1,2; Jie, Xingming1; Zhu, Haitao1; Liu, Dandan1; Peng, Weiming2; Cao, Yiming1 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2018-03-10 |
| 卷号 | 135期号:10 |
| 关键词 | Membranes Nonpolymeric Materials And Composites Oil & Gas Polyimides Separation Techniques |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.45728 |
| 文献子类 | Article |
| 英文摘要 | With MOFs of Cu-3(BTC)(2) and ZIF-8 as the dispersed phases and four polyimides with CO2 permeabilities ranging from 1.36 to 564 barrer as the continuous phase, the influence of metal organic frameworks on the gas-separation properties of mixed-matrix membranes (MMMs) was investigated. The results show that the gas permeabilities of all of the prepared MMMs greatly increased and even largely exceeded the predicted value of the Bruggeman model; for example, with the same Cu-3(BTC)(2) loading of 21.3 vol %, the O-2 permeability increase rate of our prepared Cu-3(BTC)(2)/Matrimide 5218-20 MMMs was 2.26 times, whereas that predicted by the Bruggeman model was only 1.05 times. In addition, when the gas permeability of the polymeric phase was far lower than the dispersed phase of ZIF-8 or Cu-3(BTC)(2) compared with ZIF-8, which had a particle size (R) around 150 nm, Cu-3(BTC)(2) of 5-15 mm showed a little better enhancing effect on the gas-permeation performance of the MMMs. In addition to the properties of the dispersed and continuous phases, we speculated that the ratio between R of the dispersed phase to the membrane thickness (L) played an important role for MMMs; the larger R/L was, the greater the gas permeability of the MMMs was. This speculation was initially evidenced by the ZIF-8/ODPA/TMPDA-20 MMMs with different Ls. (C) 2017 Wiley Periodicals, Inc. |
| WOS关键词 | ZEOLITIC IMIDAZOLATE FRAMEWORK ; ROOM-TEMPERATURE SYNTHESIS ; SEPARATION PROPERTIES ; COMPOSITE MEMBRANES ; COPOLYIMIDE MEMBRANES ; TRANSPORT-PROPERTIES ; HKUST-1 MEMBRANES ; MOLECULAR-SIEVE ; HOLLOW-FIBER ; PERMEABILITY |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000417601900006 |
| 出版者 | WILEY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168434]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Cao, Yiming |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.China HuaDian Sci & Technol Inst, Beijing 100070, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, Cuijia,Jie, Xingming,Zhu, Haitao,et al. Gas-permeation performance of metal organic framework/polyimide mixed-matrix membranes and additional explanation from the particle size angle[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2018,135(10). |
| APA | Duan, Cuijia,Jie, Xingming,Zhu, Haitao,Liu, Dandan,Peng, Weiming,&Cao, Yiming.(2018).Gas-permeation performance of metal organic framework/polyimide mixed-matrix membranes and additional explanation from the particle size angle.JOURNAL OF APPLIED POLYMER SCIENCE,135(10). |
| MLA | Duan, Cuijia,et al."Gas-permeation performance of metal organic framework/polyimide mixed-matrix membranes and additional explanation from the particle size angle".JOURNAL OF APPLIED POLYMER SCIENCE 135.10(2018). |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。