Li2NH-LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction
文献类型：期刊论文
| 作者 | Wang, Han2,3; Cao, Hujun4; Zhang, Weijin2,3; Chen, Jian5; Wu, Hui1; Pistidda, Claudio4; Ju, Xiaohua2; Zhou, Wei1; Wu, Guotao2; Etter, Martin6 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2018-01-26 |
| 卷号 | 24期号:6页码:1342-1347 |
| 关键词 | Hydrogen Storage Lithium Borohydride Lithium Imide Lithium Ion Conductor |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201703910 |
| 文献子类 | Article |
| 英文摘要 | Complex hydrides have played important roles in energy storage area. Here a complex hydride made of Li2NH and LiBH4 was synthesized, which has a structure tentatively indexed using an orthorhombic cell with a space group of Pna2(1) and lattice parameters of a= 10.121, b= 6.997, and c= 11.457 angstrom. The Li2NH-LiBH4 sample ( in a molar ratio of 1: 1) shows excellent hydrogenation kinetics, starting to absorb H-2 at 310 K, which is more than 100 K lower than that of pristine Li2NH. Furthermore, the Li+ ion conductivity of the Li2NH-LiBH4 sample is about 1.0 x 10(-5) Scm(-1) at room temperature, and is higher than that of either Li2NH or LiBH4 at 373 K. Those unique properties of the Li2NH-LiBH4 complex render it a promising candidate for hydrogen storage and Li ion conduction. |
| WOS关键词 | N-H SYSTEM ; STORAGE PROPERTIES ; AMIDE ; LIBH4 ; BOROHYDRIDE ; COMPOSITES ; MECHANISMS ; MIXTURES ; IMIDES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000423351800018 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168492]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wu, Guotao; Chen, Ping |
| 作者单位 | 1.NIST, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Helmholtz Zentrum Geesthacht GmbH, Inst Mat Res, Mat Technol, Max Planck Str 1, D-21502 Geesthacht, Germany 5.Chinese Acad Sci, Dalian Inst Chem Phys, Adv Rechargeable Battery Lab, Dalian 116023, Peoples R China 6.DESY, Notkestr 85, Hamburg, Germany |
| 推荐引用方式 GB/T 7714 | Wang, Han,Cao, Hujun,Zhang, Weijin,et al. Li2NH-LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(6):1342-1347. |
| APA | Wang, Han.,Cao, Hujun.,Zhang, Weijin.,Chen, Jian.,Wu, Hui.,...&Chen, Ping.(2018).Li2NH-LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction.CHEMISTRY-A EUROPEAN JOURNAL,24(6),1342-1347. |
| MLA | Wang, Han,et al."Li2NH-LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction".CHEMISTRY-A EUROPEAN JOURNAL 24.6(2018):1342-1347. |
入库方式： OAI收割
来源：大连化学物理研究所
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