Oxidative Coupling of a-O-4 Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages
文献类型：期刊论文
| 作者 | Peng, Chang2,3; Liu, Wujun1,2; Ning, Siyang2; Ge, Guangbo2; Zhao, Zongbao K.1,2,4 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2017-12-01 |
| 卷号 | 6期号:12页码:1745-1748 |
| 关键词 | Dilignols Hypervalent Compounds Oxidative Coupling Polycycles Renewable Resources Dibenzo[b d]Oxepine |
| ISSN号 | 2193-5807 |
| DOI | 10.1002/ajoc.201700529 |
| 文献子类 | Article |
| 英文摘要 | Our capability to utilize lignin as a renewable resource has been continuously expanding thanks to the information acquired through in-depth studies with various model compounds. Herein, efficient routes were devised to assemble biomass-derived building blocks for functionalized a-O-4 dilignol models. Oxidative coupling of these dilignols with hypervalent iodine(III) reagents led to two series of highly fused polycyclic products, dibenzo[b,d]oxepine and 2,7-dioxabicyclo[3,3,1]nonane derivatives. These products contain rare interlignol C-C and C-O linkages and are otherwise difficult to synthesize. Preliminary studies suggested that some of these products had moderate anticancer activity. |
| WOS关键词 | C BOND-CLEAVAGE ; HYPERVALENT IODINE(III) REAGENT ; EFFICIENT SYNTHESIS ; LIGNIN MODELS ; CATALYST ; HYDROGENOLYSIS ; DERIVATIVES ; AROMATICS ; CHEMICALS ; ACID |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000418190200012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168512]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Wujun; Zhao, Zongbao K. |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Biotechnol, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, Chang,Liu, Wujun,Ning, Siyang,et al. Oxidative Coupling of a-O-4 Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2017,6(12):1745-1748. |
| APA | Peng, Chang,Liu, Wujun,Ning, Siyang,Ge, Guangbo,&Zhao, Zongbao K..(2017).Oxidative Coupling of a-O-4 Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages.ASIAN JOURNAL OF ORGANIC CHEMISTRY,6(12),1745-1748. |
| MLA | Peng, Chang,et al."Oxidative Coupling of a-O-4 Dilignol Models Leading to Polycyclic Products with Rare Interlignol Linkages".ASIAN JOURNAL OF ORGANIC CHEMISTRY 6.12(2017):1745-1748. |
入库方式： OAI收割
来源：大连化学物理研究所
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