Autothermal reforming of model purified biogas using an extruded honeycomb monolith: A new catalyst based on nickel incorporated illite clay promoted with MgO
文献类型：期刊论文
| 作者 | Akri, Mohcin1,2,4; Achak, Ouafae2; Granger, Pascal3; Wang, Sheng4; Batiot-Dupeyrat, Catherine1; Chafik, Tarik2 |
| 刊名 | JOURNAL OF CLEANER PRODUCTION
 |
| 出版日期 | 2018-01-10 |
| 卷号 | 171页码:377-389 |
| 关键词 | Monolith Natural Clay Extrusion Magnesium Nickel Autothermal Dry Reforming |
| ISSN号 | 0959-6526 |
| DOI | 10.1016/j.jclepro.2017.09.251 |
| 文献子类 | Article |
| 英文摘要 | The dry reforming of methane was investigated using a novel catalyst based on natural illite clay to which nickel and magnesium has been added into moldable paste easily extrudated into honeycomb monolith. This approach can represent a significant breakthrough offering an alternative to conventional costly wash-coated ceramic substrates usually difficult to optimize, and a gain in efficiency thanks to the minimization of transfer limitations. The best catalytic performance were obtained with illite clay containing 8 wt.%Ni and 3 wt.%Mg, yielding to excellent conversions of CH4 and CO2 at 800 degrees C of respectively 81% and 76%. The catalytic enhancement observed on magnesium-doped systems was attributed to the stabilization of smaller Ni particles associated with the formation of NiO-MgO solid solution which slows down particle sintering. The obtained results suggest different types of nickel-support interactions in addition to improved basic properties inducing synergy effects on the rate of methane and CO2 conversion and higher resistance to deactivation phenomena. (C) 2017 Elsevier Ltd. All rights reserved. |
| WOS关键词 | FISCHER-TROPSCH SYNTHESIS ; PARTIAL OXIDATION ; NI CATALYSTS ; ENVIRONMENTAL APPLICATIONS ; HYDROGEN-PRODUCTION ; NI/MGO CATALYSTS ; COKE FORMATION ; SYNTHESIS GAS ; METHANE ; CO2 |
| WOS研究方向 | Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000418978100034 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168546]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Chafik, Tarik |
| 作者单位 | 1.Univ Poitiers, CNRS, Inst Chim Milieux & Mat Poitiers IC2MP, ENSIP,UMR 7285, 1rue Marcel Dore,TSA 41105, F-86073 Poitiers 9, France 2.Univ Abdelmalek Essaadi, Fac Sci & Tech Tangier, Lab LGCVR, UAE L01FST, Tetouan, Morocco 3.Univ Lille 1, CNRS, UCCS, UMR 8181, Cite Sci Bat C3, F-59655 Villeneuve Dascq, France 4.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Akri, Mohcin,Achak, Ouafae,Granger, Pascal,et al. Autothermal reforming of model purified biogas using an extruded honeycomb monolith: A new catalyst based on nickel incorporated illite clay promoted with MgO[J]. JOURNAL OF CLEANER PRODUCTION,2018,171:377-389. |
| APA | Akri, Mohcin,Achak, Ouafae,Granger, Pascal,Wang, Sheng,Batiot-Dupeyrat, Catherine,&Chafik, Tarik.(2018).Autothermal reforming of model purified biogas using an extruded honeycomb monolith: A new catalyst based on nickel incorporated illite clay promoted with MgO.JOURNAL OF CLEANER PRODUCTION,171,377-389. |
| MLA | Akri, Mohcin,et al."Autothermal reforming of model purified biogas using an extruded honeycomb monolith: A new catalyst based on nickel incorporated illite clay promoted with MgO".JOURNAL OF CLEANER PRODUCTION 171(2018):377-389. |
入库方式： OAI收割
来源：大连化学物理研究所
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