Chemical Foaming Coupled Self-Etching: A Multiscale Processing Strategy for Ultrahigh-Surface-Area Carbon Aerogels
文献类型：期刊论文
| 作者 | Qi, Fulai1,2; Xia, Zhangxun1; Jin, Jutao3; Fu, Xudong1; Wei, Wei1; Wang, Suli1; Sun, Gongquan1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2018-01-24 |
| 卷号 | 10期号:3页码:2819-2827 |
| 关键词 | Carbon Aerogels Chemical Foaming Self-etching Ultrahigh Surface Area Multifunctional Applications |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.7b16556 |
| 文献子类 | Article |
| 英文摘要 | Due to the unique structure, carbon-aerogels have always shown great potential for Multifunctional applications. At present, it is highly desirable but remains challenging to tailor the microstructures with respect to porosity and specific surface area to further expand its significance. A facile chemical foaming coupled self-etching strategy is developed for multiscale processing of carbon aerogels: The strategy is directly realized via: the pyrolysis of a multifunctional precursor (pentaerythritol melamine phosphate) without any special drying process and Multiple steps: In the micrometer scale, the macroporous scaffold structures with interconnected and strutted carbon nanosheets are built up by chemical-foaming from decomposition of melamine, whereas the meso / microporous nanosheets are formed via self-etching by phosphorus-containing, species. . The delicately hierarchical structures and record breaking specific surface area of 2668.4 m(2) g(-1) render the obtained carbon aerogels great potentials for absorption (324.1-593.6 g g(-1) of absorption capacities for varied organic solvents) and energy storage (338, F g(-1) of specific capacitance). The construction of such novel carbon nanoarchitecture will also shed light on the design and synthesis of multifunctional materials. |
| WOS关键词 | FIRE RETARDANT POLYMERS ; ENERGY-STORAGE ; PENTAERYTHRITOL PHOSPHATE ; AMMONIUM POLYPHOSPHATE ; THERMAL-DEGRADATION ; MELAMINE PHOSPHATE ; MESOPOROUS CARBON ; POROUS STRUCTURE ; PHOSPHORIC-ACID ; GRAPHENE OXIDE |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000423496500072 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168572]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Suli; Sun, Gongquan |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Div Fuel Cell & Battery, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Dongguan Univ Technol, Sch Environm & Architecture, Dongguan 523808, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Fulai,Xia, Zhangxun,Jin, Jutao,et al. Chemical Foaming Coupled Self-Etching: A Multiscale Processing Strategy for Ultrahigh-Surface-Area Carbon Aerogels[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(3):2819-2827. |
| APA | Qi, Fulai.,Xia, Zhangxun.,Jin, Jutao.,Fu, Xudong.,Wei, Wei.,...&Sun, Gongquan.(2018).Chemical Foaming Coupled Self-Etching: A Multiscale Processing Strategy for Ultrahigh-Surface-Area Carbon Aerogels.ACS APPLIED MATERIALS & INTERFACES,10(3),2819-2827. |
| MLA | Qi, Fulai,et al."Chemical Foaming Coupled Self-Etching: A Multiscale Processing Strategy for Ultrahigh-Surface-Area Carbon Aerogels".ACS APPLIED MATERIALS & INTERFACES 10.3(2018):2819-2827. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。