Tuning Y-zeolite based catalyst with copper for enhanced activity and selectivity in vapor phase hydrogenolysis of glycerol to 1,2-propanediol
文献类型：期刊论文
| 作者 | Mitta, Harisekhar1,2; Seelam, Prem Kumar3; Ojala, Satu3; Keiski, Riitta L.3; Balla, Putrakumar2 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2018-01-25 |
| 卷号 | 550页码:308-319 |
| 关键词 | Glycerol Selective Hydrogenolysis Acid-basic Properties Metal Dispersion Ultra-small Copper Particles 1 2-propanediol |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2017.10.019 |
| 文献子类 | Article |
| 英文摘要 | Highly dispersed copper oxide species supported on a Y-zeolite with different Si/Al ratios (5.1, 12, 30, and 60) were synthesized by an incipient wet impregnation method. The catalysts were characterized by X-ray diffraction (XRD), N-2 adsorption (BET), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffused reflectance spectroscopy (UV-DRS), N2O chemisorption, Pyridine-adsorption Fourier transform Infrared Spectroscopy (Py-FTIR), NH3 temperature programmed desorption (NH3-TPD) and temperature programmed reduction (TPR). Copper dispersion and metallic area were measured by the N2O decomposition method. The amount of Bronsted and Lewis acidic sites was analyzed by Pyridine adsorption followed by FT-IR. Performance of the prepared catalysts in vapor phase hydrogenolysis of glycerol to 1,2-propanediol was evaluated by using a fixed-bed stainless-steel reactor at 0.2 MPa and 210 degrees C. The studies revealed that the 3 wt.% CuO/Y-zeolite (Si/Al = 5.1) catalyst was highly active in glycerol hydrogenolysis showing 92% conversion of glycerol and 83% selectivity to 1,2-propanediol. This seems to originate from high dispersion of Cu, smaller Cu crystallite size, and the presence of a high amount of surface beneficial acido-basic properties. |
| WOS关键词 | SOLID ACID CATALYSTS ; ION-EXCHANGE-RESIN ; PROPYLENE-GLYCOL ; AQUEOUS-PHASE ; REACTION-MECHANISM ; CU/SIO2 CATALYSTS ; NO REDUCTION ; SI/AL RATIO ; PERFORMANCE ; OXIDATION |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000423648900032 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168614]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Mitta, Harisekhar |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Indian Inst Chem Technol, CSIR, Catalysis Div, Hyderabad 500007, Telangana, India 3.Univ Oulu, Fac Technol, Environm & Chem Engn, POB 4300, FI-90014 Oulu, Finland |
| 推荐引用方式 GB/T 7714 | Mitta, Harisekhar,Seelam, Prem Kumar,Ojala, Satu,et al. Tuning Y-zeolite based catalyst with copper for enhanced activity and selectivity in vapor phase hydrogenolysis of glycerol to 1,2-propanediol[J]. APPLIED CATALYSIS A-GENERAL,2018,550:308-319. |
| APA | Mitta, Harisekhar,Seelam, Prem Kumar,Ojala, Satu,Keiski, Riitta L.,&Balla, Putrakumar.(2018).Tuning Y-zeolite based catalyst with copper for enhanced activity and selectivity in vapor phase hydrogenolysis of glycerol to 1,2-propanediol.APPLIED CATALYSIS A-GENERAL,550,308-319. |
| MLA | Mitta, Harisekhar,et al."Tuning Y-zeolite based catalyst with copper for enhanced activity and selectivity in vapor phase hydrogenolysis of glycerol to 1,2-propanediol".APPLIED CATALYSIS A-GENERAL 550(2018):308-319. |
入库方式： OAI收割
来源：大连化学物理研究所
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