Low-temperature molar heat capacities, thermodynamic properties and crystal structure of Cu(C3N2H4)(4)(ClO4)(2)
文献类型：期刊论文
| 作者 | Pan, Lu1; Lv, Xue-Chuan1; Gao, Xiao-Han1; Tan, Zhi-Cheng2 |
| 刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
 |
| 出版日期 | 2018 |
| 卷号 | 131期号:1页码:15-23 |
| 关键词 | Copper Imidazole Crystal Structure Thermal Analysis Adiabatic Calorimetry Low-temperature Heat Capacity |
| ISSN号 | 1388-6150 |
| DOI | 10.1007/s10973-016-5697-y |
| 文献子类 | Article |
| 英文摘要 | A complex of copper perchlorate coordinated with imidazole Cu(C3N2H4)(4)(ClO4)(2) was synthesized and characterized by X-ray single-crystal diffraction. The complex is centrosymmetric in the monoclinic P2(1)/c space group. The low-temperature molar heat capacities and thermodynamic properties of the complex were studied with adiabatic calorimetry (AC). The thermodynamic functions [H-T-H-298.15] and [S-T-S-298.15] were derived in the temperature range from 80 to 370 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scanning calorimetry (DSC). The mechanism of the decomposition was deduced to be the breaking up the two Cl-O bonds of the Cl-O-Cu and the Cu-N bonds of the imidazole rings in succession. |
| WOS关键词 | COPPER(II) COMPLEXES ; THERMAL-DECOMPOSITION ; ADIABATIC CALORIMETER ; IMIDAZOLE LIGANDS ; SCHIFF-BASES ; DNA-BINDING ; CU(II) ; PERCHLORATE ; STABILITY |
| WOS研究方向 | Thermodynamics ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000419786700002 |
| 出版者 | SPRINGER |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168632]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lv, Xue-Chuan |
| 作者单位 | 1.Liaoning Shihua Univ, Coll Chem Engn & Environm, Sch Chem & Mat Sci, Fushun 113001, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Lu,Lv, Xue-Chuan,Gao, Xiao-Han,et al. Low-temperature molar heat capacities, thermodynamic properties and crystal structure of Cu(C3N2H4)(4)(ClO4)(2)[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2018,131(1):15-23. |
| APA | Pan, Lu,Lv, Xue-Chuan,Gao, Xiao-Han,&Tan, Zhi-Cheng.(2018).Low-temperature molar heat capacities, thermodynamic properties and crystal structure of Cu(C3N2H4)(4)(ClO4)(2).JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,131(1),15-23. |
| MLA | Pan, Lu,et al."Low-temperature molar heat capacities, thermodynamic properties and crystal structure of Cu(C3N2H4)(4)(ClO4)(2)".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 131.1(2018):15-23. |
入库方式： OAI收割
来源：大连化学物理研究所
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