Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture
文献类型：期刊论文
| 作者 | Qiu, Yan-Ling2; Zhong, He-Xiang2,3; Zhang, Tao-Tao1,2; Xu, Wen-Bin2; Su, Pan-Pan2; Li, Xian-Feng2,3; Zhang, Hua-Min2,3 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2018-01-24 |
| 卷号 | 10期号:3页码:2480-2489 |
| 关键词 | Carbon Dioxide Electroreduction Co2 Solubility Co2 Capture Faradaic Efficiency Gas Diffusion Electrode |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.7b15255 |
| 文献子类 | Article |
| 英文摘要 | The conversion efficiency and product selectivity of the electroreduction of carbon dioxide have been largely limited by the low CO2 solubility in aqueous solution. To relieve this problem, Cu-3(BTC)(2) (Cu-MOF) as CO2 capture agent was introduced into a carbon paper based gas diffusion electrode (GDE) in this study. The faradaic efficiencies (FEs) of CH4 on GDE with Cu-MOF weight ratio in the range of 7.5-10% are 2-3-fold higher than that of GDE without Cu-MOF addition under negative potentials (-2.3 to -2.5 V vs SCE), and the FE of the competitive hydrogen evolution reaction (HER) is reduced to 30%. This work paves the way to develop GDE with high catalytic activity for ERC. |
| WOS关键词 | GAS-DIFFUSION ELECTRODES ; ZEOLITIC IMIDAZOLATE FRAMEWORKS ; ELECTROCATALYTIC REDUCTION ; HIGH-PRESSURE ; COPPER ; ELECTROREDUCTION ; ETHYLENE ; SEPARATION ; NANOWIRES ; CATALYSTS |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000423496500035 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168640]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xian-Feng; Zhang, Hua-Min |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China 3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Yan-Ling,Zhong, He-Xiang,Zhang, Tao-Tao,et al. Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(3):2480-2489. |
| APA | Qiu, Yan-Ling.,Zhong, He-Xiang.,Zhang, Tao-Tao.,Xu, Wen-Bin.,Su, Pan-Pan.,...&Zhang, Hua-Min.(2018).Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture.ACS APPLIED MATERIALS & INTERFACES,10(3),2480-2489. |
| MLA | Qiu, Yan-Ling,et al."Selective Electrochemical Reduction of Carbon Dioxide Using Cu Based Metal Organic Framework for CO2 Capture".ACS APPLIED MATERIALS & INTERFACES 10.3(2018):2480-2489. |
入库方式： OAI收割
来源：大连化学物理研究所
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