Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application
文献类型:期刊论文
作者 | Chu, Weifeng1,2; Chen, Fucun1; Guo, Ce1,2; Li, Xiujie1; Zhu, Xiangxue1; Gao, Yang1; Xie, Sujuan1; Liu, Shenglin1; Jiang, Nan3; Xu, Longya1 |
刊名 | CHINESE JOURNAL OF CATALYSIS
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出版日期 | 2017-11-01 |
卷号 | 38期号:11页码:1880-1887 |
关键词 | Fer Zeolite Piperidine Crystallization Process Mww Zeolite Skeletal Isomerization |
ISSN号 | 0253-9837 |
DOI | 10.1016/S1872-2067(17)62906-1 |
文献子类 | Article |
英文摘要 | The synthesis of ferrierite (FER) zeolite using piperidine as an organic structure-directing agent was investigated. X-ray diffraction, X-ray fluorescence, N-2-adsorption, and scanning electron microscopy were used to characterize the crystal phases, textural properties, and particle morphologies of the zeolite samples. The crystallization behavior of the FER zeolite was found to be directly related to crystallization temperature. At 150 degrees C, pure FER phase was observed throughout crystallization. At 160-170 degrees C, MWW phase appeared first and gradually transformed into FER phase over time, indicating that the FER phase was thermodynamically favored. In the piperidine-Na2O-H2O synthetic system, alkalinity proved to be the crucial factor determining the size and textural properties of FER zeolite. Furthermore, the obtained FER samples exhibited good catalytic performance in the skeletal isomerization of 1-butene. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
WOS关键词 | 1-BUTENE SKELETAL ISOMERIZATION ; FERRIERITE ; SYSTEM ; HYDROCARBONS ; TETRAMETHYLAMMONIUM ; RECRYSTALLIZATION ; CONVERSION ; TEMPLATE ; MCM-49 ; ZSM-35 |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000424064600012 |
出版者 | SCIENCE PRESS |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168646] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Li, Xiujie; Xu, Longya |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Nanjing Rongxin Chem Co Ltd, Nanjing 210047, Jiangsu, Peoples R China |
推荐引用方式 GB/T 7714 | Chu, Weifeng,Chen, Fucun,Guo, Ce,et al. Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(11):1880-1887. |
APA | Chu, Weifeng.,Chen, Fucun.,Guo, Ce.,Li, Xiujie.,Zhu, Xiangxue.,...&Xu, Longya.(2017).Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application.CHINESE JOURNAL OF CATALYSIS,38(11),1880-1887. |
MLA | Chu, Weifeng,et al."Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application".CHINESE JOURNAL OF CATALYSIS 38.11(2017):1880-1887. |
入库方式: OAI收割
来源:大连化学物理研究所
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