中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application

文献类型:期刊论文

作者Chu, Weifeng1,2; Chen, Fucun1; Guo, Ce1,2; Li, Xiujie1; Zhu, Xiangxue1; Gao, Yang1; Xie, Sujuan1; Liu, Shenglin1; Jiang, Nan3; Xu, Longya1
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2017-11-01
卷号38期号:11页码:1880-1887
关键词Fer Zeolite Piperidine Crystallization Process Mww Zeolite Skeletal Isomerization
ISSN号0253-9837
DOI10.1016/S1872-2067(17)62906-1
文献子类Article
英文摘要The synthesis of ferrierite (FER) zeolite using piperidine as an organic structure-directing agent was investigated. X-ray diffraction, X-ray fluorescence, N-2-adsorption, and scanning electron microscopy were used to characterize the crystal phases, textural properties, and particle morphologies of the zeolite samples. The crystallization behavior of the FER zeolite was found to be directly related to crystallization temperature. At 150 degrees C, pure FER phase was observed throughout crystallization. At 160-170 degrees C, MWW phase appeared first and gradually transformed into FER phase over time, indicating that the FER phase was thermodynamically favored. In the piperidine-Na2O-H2O synthetic system, alkalinity proved to be the crucial factor determining the size and textural properties of FER zeolite. Furthermore, the obtained FER samples exhibited good catalytic performance in the skeletal isomerization of 1-butene. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词1-BUTENE SKELETAL ISOMERIZATION ; FERRIERITE ; SYSTEM ; HYDROCARBONS ; TETRAMETHYLAMMONIUM ; RECRYSTALLIZATION ; CONVERSION ; TEMPLATE ; MCM-49 ; ZSM-35
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000424064600012
出版者SCIENCE PRESS
源URL[http://cas-ir.dicp.ac.cn/handle/321008/168646]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Li, Xiujie; Xu, Longya
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Nanjing Rongxin Chem Co Ltd, Nanjing 210047, Jiangsu, Peoples R China
推荐引用方式
GB/T 7714
Chu, Weifeng,Chen, Fucun,Guo, Ce,et al. Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(11):1880-1887.
APA Chu, Weifeng.,Chen, Fucun.,Guo, Ce.,Li, Xiujie.,Zhu, Xiangxue.,...&Xu, Longya.(2017).Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application.CHINESE JOURNAL OF CATALYSIS,38(11),1880-1887.
MLA Chu, Weifeng,et al."Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application".CHINESE JOURNAL OF CATALYSIS 38.11(2017):1880-1887.

入库方式: OAI收割

来源:大连化学物理研究所

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