Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism
文献类型：期刊论文
| 作者 | Gupta, Neeraj1,2; Khavryuchenko, Oleksiy3,4; Wen, Guodong1; Wu, Kuang-Hsu1; Su, Dangsheng1,5 |
| 刊名 | CARBON
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 130页码:714-723 |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2018.01.045 |
| 文献子类 | Article |
| 英文摘要 | Carbon is demonstrated as a mild and transition metal free catalyst for the preparation of N-rich heterocyclic compounds for the first time. The surface > C=O groups on nanodiamonds were identified as an active site, which most probably generates imidogene as a reactive species that triggers the reaction. The experimental results supported with density functional theory calculations were used to reveal a new reaction pathway, different from the conventional homogeneous one that indicates involvement of nitrogen radicals in the reaction. (c) 2018 Elsevier Ltd. All rights reserved. |
| WOS关键词 | METAL-FREE CATALYST ; CARBON NANOTUBES ; OXIDATIVE DEHYDROGENATION ; GRAPHENE OXIDE ; HYDRAZINE ; EFFICIENT ; NANODIAMONDS ; EXCHANGE ; GLYCEROL ; BENZENE |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000424889200084 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168674]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Su, Dangsheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 2.Shoolini Univ, Sch Chem, Fac Basic Sci, Solan 173229, HP, India 3.TMM LLC, Res & Dev Dept, Volodymyrska Str 49a, UA-01601 Kiev, Ukraine 4.Ctr Res Mol Modeling, Montreal, PQ H4B 1R6, Canada 5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gupta, Neeraj,Khavryuchenko, Oleksiy,Wen, Guodong,et al. Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism[J]. CARBON,2018,130:714-723. |
| APA | Gupta, Neeraj,Khavryuchenko, Oleksiy,Wen, Guodong,Wu, Kuang-Hsu,&Su, Dangsheng.(2018).Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism.CARBON,130,714-723. |
| MLA | Gupta, Neeraj,et al."Carbocatalysing the preparation of N-Rich heterocycles with an unprecedented mechanism".CARBON 130(2018):714-723. |
入库方式： OAI收割
来源：大连化学物理研究所
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