A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts
文献类型：期刊论文
| 作者 | Li, Wenhui1; Wang, Haozhi1; Jiang, Xiao3,4; Zhu, Jie1; Liu, Zhongmin2; Guo, Xinwen1; Song, Chunshan1,3,4 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:14页码:7651-7669 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c7ra13546g |
| 文献子类 | Review |
| 英文摘要 | CO2 hydrogenation to hydrocarbons is a promising way of making waste to wealth and energy storage, which also solves the environmental and energy issues caused by CO2 emissions. Much efforts and research are aimed at the conversion of CO2 via hydrogenation to various value-added hydrocarbons, such as CH4, lower olefins, gasoline, or long-chain hydrocarbons catalyzed by different catalysts with various mechanisms. This review provides an overview of advances in CO2 hydrogenation to hydrocarbons that have been achieved recently in terms of catalyst design, catalytic performance and reaction mechanism from both experiments and density functional theory calculations. In addition, the factors influencing the performance of catalysts and the first C-C coupling mechanism through different routes are also revealed. The fundamental factor for product selectivity is the surface H/C ratio adjusted by active metals, supports and promoters. Furthermore, the technical and application challenges of CO2 conversion into useful fuels/chemicals are also summarized. To meet these challenges, future research directions are proposed in this review. |
| WOS关键词 | FISCHER-TROPSCH SYNTHESIS ; CARBON-DIOXIDE METHANATION ; WATER-GAS SHIFT ; HIGHLY SELECTIVE CONVERSION ; DENSITY-FUNCTIONAL THEORY ; METAL-ORGANIC FRAMEWORKS ; CHAIN GROWTH-MECHANISM ; SYNTHETIC NATURAL-GAS ; IRON-BASED CATALYST ; METHANOL SYNTHESIS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000425647000039 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168688]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Guo, Xinwen; Song, Chunshan |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Penn State Univ, Clean Fuels & Catalysis Program, PSU DUT Joint Ctr Energy Res, Dept Energy & Mineral Engn,EMS Energy Inst, University Pk, PA 16802 USA 4.Penn State Univ, Clean Fuels & Catalysis Program, PSU DUT Joint Ctr Energy Res, Dept Chem Engn,EMS Energy Inst, University Pk, PA 16802 USA |
| 推荐引用方式 GB/T 7714 | Li, Wenhui,Wang, Haozhi,Jiang, Xiao,et al. A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts[J]. RSC ADVANCES,2018,8(14):7651-7669. |
| APA | Li, Wenhui.,Wang, Haozhi.,Jiang, Xiao.,Zhu, Jie.,Liu, Zhongmin.,...&Song, Chunshan.(2018).A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts.RSC ADVANCES,8(14),7651-7669. |
| MLA | Li, Wenhui,et al."A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts".RSC ADVANCES 8.14(2018):7651-7669. |
入库方式： OAI收割
来源：大连化学物理研究所
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