Highly efficient porous organic copolymer supported Rh catalysts for heterogeneous hydroformylation of butenes
文献类型：期刊论文
| 作者 | Wang, Yuqing1,3; Yan, Li1; Li, Cunyao1; Jiang, Miao1; Wang, Wenlong1; Ding, Yunjie1,2 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2018-02-05 |
| 卷号 | 551页码:98-105 |
| 关键词 | HydrOformylation Of Butene Porous Organic Copolymers Synergetic Effect |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2017.12.013 |
| 文献子类 | Article |
| 英文摘要 | Porous organic copolymer (denoted as CPOL-BP&P) was afforded through the copolymerization of vinyl biphephos and tris(4-vinylphenyl)phosphine monomers under solvothermal conditions, and followed with impregnation method provided a highly efficient Rh/CPOL-BP&P catalyst with high activity (TOF = 11,200 h(-1)) and regioselectivity (the ratio of linear to branched aldehydes, l:b = 62.2) for heterogeneous hydroformylation of 1-butene. High regioselectivity was also obtained in the hydroformylation of butene mixture (2-butene: l:b = 55.8, isomeric mixture of butenes: l:b = 56.0). The Rh/CPOL-BP&P catalysts were thoroughly characterized by means of nitrogen sorption isotherms, in situ FT-IR, XPS, solid-state P-31 MAS NMR, HAADF-STEM, SEM and TEM. The formation of unique coordination bonds with Rh species in the polymer skeleton was determined. Heterogeneous hydroformylation of butenes was effectively realized due to a synergetic effect between PPh3 moiety and biphephos moiety. |
| WOS关键词 | FIXED-BED HYDROFORMYLATION ; IONIC LIQUID ; BITE-ANGLE ; LIGANDS ; POLYMERS ; OLEFINS ; FEED |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:000425555600010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168714]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yan, Li; Ding, Yunjie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yuqing,Yan, Li,Li, Cunyao,et al. Highly efficient porous organic copolymer supported Rh catalysts for heterogeneous hydroformylation of butenes[J]. APPLIED CATALYSIS A-GENERAL,2018,551:98-105. |
| APA | Wang, Yuqing,Yan, Li,Li, Cunyao,Jiang, Miao,Wang, Wenlong,&Ding, Yunjie.(2018).Highly efficient porous organic copolymer supported Rh catalysts for heterogeneous hydroformylation of butenes.APPLIED CATALYSIS A-GENERAL,551,98-105. |
| MLA | Wang, Yuqing,et al."Highly efficient porous organic copolymer supported Rh catalysts for heterogeneous hydroformylation of butenes".APPLIED CATALYSIS A-GENERAL 551(2018):98-105. |
入库方式： OAI收割
来源：大连化学物理研究所
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