Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols
文献类型：期刊论文
| 作者 | Xia, Jintao1,2; Huang, Zhipeng1,2; Zhou, Xukai1,2; Yang, Xifa1,2; Wang, Feng1; Li, Xingwei1 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018-02-02 |
| 卷号 | 20期号:3页码:740-743 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b03881 |
| 文献子类 | Article |
| 英文摘要 | Rhodium(Ill)-catalyzed C-H activation of (hetero)arenes and redox-neutral coupling with 2-carboxyl allylic alcohols has been realized for the construction of beta-aryl ketones. This reaction occurred efficiently at a relatively low catalyst loading via initial dehydrogenative alkylation to give a beta-keto carboxylic acid, followed by decarboxylation. |
| WOS关键词 | C-H ACTIVATION ; BOND FORMATION ; CARBOXYLIC-ACIDS ; SMILES REARRANGEMENT ; DIRECTING GROUP ; HECK REACTION ; FUNCTIONALIZATION ; ALKYLATION ; HYDROGEN ; ARENES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000424729800062 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168750]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Jintao,Huang, Zhipeng,Zhou, Xukai,et al. Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols[J]. ORGANIC LETTERS,2018,20(3):740-743. |
| APA | Xia, Jintao,Huang, Zhipeng,Zhou, Xukai,Yang, Xifa,Wang, Feng,&Li, Xingwei.(2018).Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols.ORGANIC LETTERS,20(3),740-743. |
| MLA | Xia, Jintao,et al."Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols".ORGANIC LETTERS 20.3(2018):740-743. |
入库方式： OAI收割
来源：大连化学物理研究所
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