Carbon Modification of Nickel Catalyst for Depolymerization of Oxidized Lignin to Aromatics
文献类型：期刊论文
| 作者 | Wang, Min; Zhang, Xiaochen; Li, Hongji; Lu, Jianmin; Liu, Meijiang; Wang, Feng |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018-02-01 |
| 卷号 | 8期号:2页码:1614-1620 |
| 关键词 | C-o Cleavage Heterogeneous Catalysis Nickel Lignin Supported Catalyst |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.7b03475 |
| 文献子类 | Article |
| 英文摘要 | Catalytic valorization of lignin is a sustainable way to provide aromatics for the human society, which depends on the electronic structure of catalytic sites. We herein report the preparation of a carbon-modified nickel catalyst via carbothermal reduction of Ni-doped layered double hydroxides. Lignosulfonate (LS), a lignin resource from the pulp industry, was used as a renewable carbon precursor. The carbon residues in the nickel surface layer changed the 3d electron distribution of nickel, which was highly selective for the C-O bond hydrogenolysis of lignin into aromatics, and 22 wt % total mass yields of aromatics were achieved from hydrogenolysis of oxidized birch lignin. |
| WOS关键词 | O BOND-CLEAVAGE ; ALUMINA-SUPPORTED NICKEL ; MODEL COMPOUNDS ; SUBSURFACE CARBON ; ARYL ETHERS ; C-C ; OXIDATIVE CLEAVAGE ; PHENOLIC MONOMERS ; NI/SIO2 CATALYST ; FORMIC-ACID |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000424735000104 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168774]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Feng |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Min,Zhang, Xiaochen,Li, Hongji,et al. Carbon Modification of Nickel Catalyst for Depolymerization of Oxidized Lignin to Aromatics[J]. ACS CATALYSIS,2018,8(2):1614-1620. |
| APA | Wang, Min,Zhang, Xiaochen,Li, Hongji,Lu, Jianmin,Liu, Meijiang,&Wang, Feng.(2018).Carbon Modification of Nickel Catalyst for Depolymerization of Oxidized Lignin to Aromatics.ACS CATALYSIS,8(2),1614-1620. |
| MLA | Wang, Min,et al."Carbon Modification of Nickel Catalyst for Depolymerization of Oxidized Lignin to Aromatics".ACS CATALYSIS 8.2(2018):1614-1620. |
入库方式： OAI收割
来源：大连化学物理研究所
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