Highly Efficient Oxidation of Ethyl Lactate to Ethyl Pyruvate Catalyzed by TS-1 Under Mild Conditions
文献类型：期刊论文
| 作者 | Lu, Tianliang1,2; Zou, Junpeng2; Zhan, Yuzhong2; Yang, Xiaomei1; Wen, Yiqiang1; Wang, Xiangyu1; Zhou, Lipeng1; Xu, Jie3 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018-02-01 |
| 卷号 | 8期号:2页码:1287-1296 |
| 关键词 | Ethyl Lactate Ethyl Pyruvate Ts-1 Catalytic Oxidation Hydrogen Peroxide |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.7b03558 |
| 文献子类 | Article |
| 英文摘要 | Highly efficient oxidation of ethyl lactate (ELA) to ethyl pyruvate (EP) was realized over TS-1 in the presence of aqueous H2O2 (30 wt %) at low temperature without other solvent. A 100% ELA conversion and 97.8% EP yield were obtained at 50 degrees C after 9 h. The conversion rate of ELA is sensitive to the reaction temperature. High reaction temperature (70 degrees C) leads to an increase in conversion rate of ELA but causes the fast hydrolysis and decarboxylation of EP to form byproducts of acetic acid and CO2. On the basis of the characterization (pyridine-FTIR and UV-vis) and reaction results, active species of Ti(OOH) were proven. In addition, a nonradical mechanism for conversion of ELA to EP for this catalytic system was proposed. By kinetic analysis, the formation of Ti(OOH) is confirmed as the rate-determining step. The apparent activation energy (103.4 kJ mol(-1)) was also obtained. Furthermore, TS-1 was highly stable for the oxidation of ethyl lactate. There were almost no change in ELA conversion and EP yield throughout 10 reaction runs. |
| WOS关键词 | SN-BETA ZEOLITES ; LACTIC-ACID ; CYCLOHEXANONE AMMOXIMATION ; TITANIUM SILICALITE-1 ; REACTION-KINETICS ; ESCHERICHIA-COLI ; OXIDE CATALYSTS ; ALLYL CHLORIDE ; ACTIVE-SITES ; DEHYDROGENATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000424735000069 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168786]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhou, Lipeng |
| 作者单位 | 1.Zhengzhou Univ, Coll Chem & Mol Engn, 100 Kexue Rd, Zhengzhou 450001, Henan, Peoples R China 2.Zhengzhou Univ, Sch Chem Engn & Energy, 100 Kexue Rd, Zhengzhou 450001, Henan, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Tianliang,Zou, Junpeng,Zhan, Yuzhong,et al. Highly Efficient Oxidation of Ethyl Lactate to Ethyl Pyruvate Catalyzed by TS-1 Under Mild Conditions[J]. ACS CATALYSIS,2018,8(2):1287-1296. |
| APA | Lu, Tianliang.,Zou, Junpeng.,Zhan, Yuzhong.,Yang, Xiaomei.,Wen, Yiqiang.,...&Xu, Jie.(2018).Highly Efficient Oxidation of Ethyl Lactate to Ethyl Pyruvate Catalyzed by TS-1 Under Mild Conditions.ACS CATALYSIS,8(2),1287-1296. |
| MLA | Lu, Tianliang,et al."Highly Efficient Oxidation of Ethyl Lactate to Ethyl Pyruvate Catalyzed by TS-1 Under Mild Conditions".ACS CATALYSIS 8.2(2018):1287-1296. |
入库方式： OAI收割
来源：大连化学物理研究所
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