Efficient Synthesis of 2,5-Dicyanofuran from Biomass-Derived 2,5-Diformylfuran via an Oximation-Dehydration Strategy
文献类型：期刊论文
| 作者 | Xu, Yongming1,2; Jia, Xiuquan1; Ma, Jiping1; Gao, Jin1; Xia, Fei1,2; Li, Xiaofang1,2; Xu, Jie1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 6期号:3页码:2888-2892 |
| 关键词 | Sustainable Chemistry Aromatic Dinitrile Hydroxylamine Dehydration Of Aldoximes 2 5-diformylfuran |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.7b03913 |
| 文献子类 | Article |
| 英文摘要 | Aromatic dinitriles show promise as a pivotal building block in polymer and pharmaceutical chemistry, and their production from biomass-based alcohols or aldehydes is highly desirable. In this work, for the first time, 2,5-dicyanofuran was efficiently synthesized from biomass-derived 2,5-diformylfuran via a two-step procedure. 2,5-Diformylfuran was first converted to 2,5-diformylfuran dioxime with 90% isolated yield in water. Hydroxylamine instead of ammonia used as nitrogen source is the key to this strategy, which avoids the polymerization reaction of intermediate aldimine. The subsequent dehydration reaction of 2,5-diformylfuran dioxime afforded 2,5-dicyanofuran in 82% isolated yield over an effective and recyclable solid acid catalyst Amberlyst-15. This approach demonstrates the feasibility of synthesis of reactive dinitriles from dialdehydes without using toxic cyanides or halides. |
| WOS关键词 | ONE-STEP SYNTHESIS ; AEROBIC OXIDATION ; HETEROGENEOUS CATALYSIS ; HIGHLY EFFICIENT ; ONE-POT ; NITRILES ; CONVERSION ; ALDOXIMES ; HYDROCYANATION ; HYDROXYLAMINE |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000427092900009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168860]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Ma, Jiping; Xu, Jie |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19 Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Yongming,Jia, Xiuquan,Ma, Jiping,et al. Efficient Synthesis of 2,5-Dicyanofuran from Biomass-Derived 2,5-Diformylfuran via an Oximation-Dehydration Strategy[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(3):2888-2892. |
| APA | Xu, Yongming.,Jia, Xiuquan.,Ma, Jiping.,Gao, Jin.,Xia, Fei.,...&Xu, Jie.(2018).Efficient Synthesis of 2,5-Dicyanofuran from Biomass-Derived 2,5-Diformylfuran via an Oximation-Dehydration Strategy.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(3),2888-2892. |
| MLA | Xu, Yongming,et al."Efficient Synthesis of 2,5-Dicyanofuran from Biomass-Derived 2,5-Diformylfuran via an Oximation-Dehydration Strategy".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.3(2018):2888-2892. |
入库方式： OAI收割
来源：大连化学物理研究所
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