Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand
文献类型：期刊论文
| 作者 | Wang, Qingfu1,2; Chai, Huining1,2; Yu, Zhengkun2,3 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2018-02-26 |
| 卷号 | 37期号:4页码:584-591 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/acs.organomet.7b00902 |
| 文献子类 | Article |
| 英文摘要 | Ruthenium(II) hydride complexes bearing a pyrazolyl-(2-indol-1-yl)-pyridine ligand were synthesized and structurally characterized by NMR analysis and X-ray single crystal crystallographic determinations. These complexes efficiently catalyzed acceptorless dehydrogenation of N-heterocycles and secondary alcohols, respectively, exhibiting highly catalytic activity with a broad substrate scope. The present work has established a strategy to construct highly active transition metal complex catalysts and provides an atom-economical and environmentally benign protocol for the synthesis of aromatic N-heterocydic compounds and ketones. |
| WOS关键词 | ASYMMETRIC TRANSFER HYDROGENATION ; TETRAHYDRO-BETA-CARBOLINES ; CATALYSTS BEARING ; REVERSIBLE DEHYDROGENATION ; IMIDAZOLYL LIGAND ; NITROGEN-HETEROCYCLES ; ARYL CHLORIDES ; NNN LIGAND ; KETONES ; OXIDATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000426618800011 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168870]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhengkun |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Qingfu,Chai, Huining,Yu, Zhengkun. Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand[J]. ORGANOMETALLICS,2018,37(4):584-591. |
| APA | Wang, Qingfu,Chai, Huining,&Yu, Zhengkun.(2018).Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand.ORGANOMETALLICS,37(4),584-591. |
| MLA | Wang, Qingfu,et al."Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand".ORGANOMETALLICS 37.4(2018):584-591. |
入库方式： OAI收割
来源：大连化学物理研究所
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