Simultaneous two-electron trarisfer from photoirradiated semiconductor to molecular catalyst
文献类型：期刊论文
| 作者 | Xu, Yuxing1,2; Liu, Taifeng1; Yin, Heng1,2; Yao, Tingting1; Wang, Xiuli1; Han, Hongxian1; Li, Can1 |
| 刊名 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
 |
| 出版日期 | 2018-03-15 |
| 卷号 | 355页码:332-337 |
| 关键词 | Photocatalysis Electron Transfer Tio2 Cobaloxime Cobalt Complex Multi-electron Transfer Charge Transfer |
| ISSN号 | 1010-6030 |
| DOI | 10.1016/j.jphotochem.2017.08.021 |
| 文献子类 | Article |
| 英文摘要 | Better understanding the multi-electron transfer processes in photocatalytic water splitting and CO2 reduction is crucial for the development of the efficient artificial photosynthesis systems for production of solar fuels. Here, the multi-electron transfer-from TiO2 to cobaloxime (a molecular catalyst) in 'cobaloxime/TiO2 hybrid systems has been studied in detail in the presence of methanol. The results of the thermodynamic study revealed that simultaneous two-electron transfer from TiO2 to cobaloxime is the most plausible account for the interpretation of the observed photocatalytic (activities. And the accumulation of photogenerated electrons in TiO2 is an essential prerequisite for simultaneous two electron transfer from semiconductor to the molecular catalyst based on the analysis of charge transfer processes. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | VISIBLE-LIGHT ; HYDROGEN EVOLUTION ; TIO2 NANOPARTICLES ; CADMIUM-SULFIDE ; SINGLET FISSION ; H2O2 PRODUCTION ; REDUCTION ; CONVERSION ; H-2 ; PHOTOCATALYSIS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000428227500049 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168966]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Han, Hongxian; Li, Can |
| 作者单位 | 1.Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat iCheM, Div Solar Energy, State Key Lab Catalysis,Dalian Inst Chem Phys,Dal, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Yuxing,Liu, Taifeng,Yin, Heng,et al. Simultaneous two-electron trarisfer from photoirradiated semiconductor to molecular catalyst[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2018,355:332-337. |
| APA | Xu, Yuxing.,Liu, Taifeng.,Yin, Heng.,Yao, Tingting.,Wang, Xiuli.,...&Li, Can.(2018).Simultaneous two-electron trarisfer from photoirradiated semiconductor to molecular catalyst.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,355,332-337. |
| MLA | Xu, Yuxing,et al."Simultaneous two-electron trarisfer from photoirradiated semiconductor to molecular catalyst".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 355(2018):332-337. |
入库方式： OAI收割
来源：大连化学物理研究所
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