Crystal-Plane-Dependent Activity of Spinel Co3O4 Towards Water Splitting and the Oxygen Reduction Reaction
文献类型：期刊论文
| 作者 | Liu, Qianfeng1,2; Chen, Zhiping1,2; Yan, Zhao1; Wang, Yao1,2; Wang, Erdong1; Wang, Sheng1; Wang, Shudong1; Sun, Gongquan1 |
| 刊名 | CHEMELECTROCHEM
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 5期号:7页码:1080-1086 |
| 关键词 | Electrochemistry Co3o4 Oxygen Evolution Reaction Oxygen Reduction Reaction Hydrogen Evolution Reaction |
| ISSN号 | 2196-0216 |
| DOI | 10.1002/celc.201701302 |
| 文献子类 | Article |
| 英文摘要 | Insights into the relationship between the crystal planes of metal oxides and the catalytic activity of the oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and hydrogen evolution reaction (HER) are essential for developing efficient renewable energy technologies. Herein, spinel Co3O4 nanomaterials were synthesized controllably with the specified morphologies of nanocubes, nanosheets, and nanoplates with different exposed planes of {100}, {110}, and {111}, respectively. The effects of the crystal planes of Co3O4 on the activity for the OER, ORR, and HER were subsequently investigated in alkaline media. Different electrocatalytic performances are possibly attributed to the abundance ratios of Co3+/Co2+ over the different exposed planes. The surface Co3+ ions exhibit higher activity for the OER and HER, whereas the surface Co2+ ions exhibit better performance for the ORR; moreover, higher electroconductivity enhances the polarization current for ORR and HER except OER. |
| WOS关键词 | EVOLUTION REACTION CATALYST ; CARBON NANOTUBES ; BIFUNCTIONAL ELECTROCATALYSTS ; EFFICIENT ELECTROCATALYSTS ; CONTROLLABLE SYNTHESIS ; ALKALINE MEDIA ; COBALT ; PERFORMANCE ; SURFACE ; OXIDES |
| WOS研究方向 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000429413700012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168974]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Erdong; Wang, Sheng; Wang, Shudong; Sun, Gongquan |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Qianfeng,Chen, Zhiping,Yan, Zhao,et al. Crystal-Plane-Dependent Activity of Spinel Co3O4 Towards Water Splitting and the Oxygen Reduction Reaction[J]. CHEMELECTROCHEM,2018,5(7):1080-1086. |
| APA | Liu, Qianfeng.,Chen, Zhiping.,Yan, Zhao.,Wang, Yao.,Wang, Erdong.,...&Sun, Gongquan.(2018).Crystal-Plane-Dependent Activity of Spinel Co3O4 Towards Water Splitting and the Oxygen Reduction Reaction.CHEMELECTROCHEM,5(7),1080-1086. |
| MLA | Liu, Qianfeng,et al."Crystal-Plane-Dependent Activity of Spinel Co3O4 Towards Water Splitting and the Oxygen Reduction Reaction".CHEMELECTROCHEM 5.7(2018):1080-1086. |
入库方式： OAI收割
来源：大连化学物理研究所
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