Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin
文献类型：期刊论文
| 作者 | Cong, Yu1; Tang, Hao1,2; Li, Ning1,3; Li, Guangyi1; Wang, Wentao1; Wang, Aiqin1,3; Wang, Xiaodong1 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 6期号:4页码:5645-5652 |
| 关键词 | Carbohydrates Dehydration 5-hydroxymethylfurfural Lignosulfonate Acidic Resin |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b00757 |
| 文献子类 | Article |
| 英文摘要 | Lignosulfonate-based renewable solid acids were first utilized as effective catalysts for fructose dehydration to produce 5-hydroxymethylfurfural (HMF). Among the investigated catalysts, the LF resin synthesized with formaldehyde and sodium lignosulfonate demonstrated the highest activity and good stability. Over it, similar to 90% HMF carbon yield was reached at 393 K. On the basis of the characterization results of N-2-physisorption, chemical titration, and microcalorimetric measurement of NH3 adsorption, the outstanding performance of LF resin should be interpreted by its higher acid strength and/or the synergistic effect of adjacent -SO3H, -COOH and phenolic -OH surface functional groups. We also explored the applicability of the LF resin for HMF production using other cheaper carbohydrates. Here, 73% HMF carbon yield was obtained from inulin hydrolysis/dehydration after the reaction was conducted over the LF resin at 393 K for 2.5 h. |
| WOS关键词 | TEMPERATURE CARBON MATERIALS ; HIGH-YIELD PRODUCTION ; AEROBIC OXIDATION ; SOLID ACID ; 2,5-FURANDICARBOXYLIC ACID ; CATALYTIC CONVERSION ; EFFICIENT PRODUCTION ; BIOMASS ; CHEMICALS ; SO3H |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000429285800133 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168998]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Ning |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 4S7 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cong, Yu,Tang, Hao,Li, Ning,et al. Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(4):5645-5652. |
| APA | Cong, Yu.,Tang, Hao.,Li, Ning.,Li, Guangyi.,Wang, Wentao.,...&Wang, Xiaodong.(2018).Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(4),5645-5652. |
| MLA | Cong, Yu,et al."Dehydration of Carbohydrates to 5-Hydroxymethylfurfural over Lignosulfonate-Based Acidic Resin".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.4(2018):5645-5652. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。