Zn(II) porphyrin-based photocatalytic synthesis of Cu nanoparticles for electrochemical reduction of CO2
文献类型：期刊论文
| 作者 | Zhang, Xue1,2; Zhang, Siyu1,2; Liu, Huiyuan1,2,3,4; Lv, Yang1,2; Hou, Zhongjun5; Song, Yujiang1,2 |
| 刊名 | JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 22期号:5页码:406-412 |
| ISSN号 | 1088-4246 |
| 关键词 | Photocatalysis Zinc(Ii) Porphyrin Cu Nanoparticles Electrochemical Reduction Of Co2 |
| DOI | 10.1142/S1088424618500293 |
| 文献子类 | Article |
| 英文摘要 | Copper nanoparticles frequently exhibit unique electrocatalytic activity for the electrochemical reduction of carbon dioxide. However, the synthesis of Cu nanoparticles in aqueous systems remains rare. Herein, we report the synthesis of copper nanoparticles by using a zinc(II) porphyrin-based photocatalytic method in the presence of polyacrylic acid sodium salt (PAA) in water under visible light irradiation, leading to a series of Cu nanoparticles with relatively small average sizes ranging from 69 to 97 nm. PAA molecules adsorbed on Cu nanoparticles were simply removed by washing with copious amount of water. The purified Cu nanoparticles show some activity toward the electrochemical reduction of carbon dioxide as evidenced by linear sweep voltammetry (LSV) and gas chromatography (GC). |
| WOS关键词 | COPPER NANOCRYSTALS ; HYDROGEN-PRODUCTION ; NANOSTRUCTURES ; NANOWIRES ; ELECTROREDUCTION ; PHTHALOCYANINES ; OPPORTUNITIES ; SELECTIVITY ; CHALLENGES ; COMPLEXES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WORLD SCI PUBL CO INC |
| WOS记录号 | WOS:000430364200003 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169002]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Song, Yujiang |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Dalian Univ Technol, Sch Chem Engn, Lab Electrochem Engn, Dalian 116024, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Labs Clean Energy, Dalian 116023, Liaoning, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 5.Sunrise Power Co Ltd, Natl Engn Res Ctr Fuel Cell & Hydrogen Technol, Dalian 116085, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xue,Zhang, Siyu,Liu, Huiyuan,et al. Zn(II) porphyrin-based photocatalytic synthesis of Cu nanoparticles for electrochemical reduction of CO2[J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES,2018,22(5):406-412. |
| APA | Zhang, Xue,Zhang, Siyu,Liu, Huiyuan,Lv, Yang,Hou, Zhongjun,&Song, Yujiang.(2018).Zn(II) porphyrin-based photocatalytic synthesis of Cu nanoparticles for electrochemical reduction of CO2.JOURNAL OF PORPHYRINS AND PHTHALOCYANINES,22(5),406-412. |
| MLA | Zhang, Xue,et al."Zn(II) porphyrin-based photocatalytic synthesis of Cu nanoparticles for electrochemical reduction of CO2".JOURNAL OF PORPHYRINS AND PHTHALOCYANINES 22.5(2018):406-412. |
入库方式： OAI收割
来源：大连化学物理研究所
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