Advances in catalytic transformations of carbohydrates and lignin in ionic liquids and mechanistic studies
文献类型：期刊论文
| 作者 | Zhang, Cheng2; Yang, Yiwen1,3; Zhang, Z. Conrad3 |
| 刊名 | WILEY INTERDISCIPLINARY REVIEWS-ENERGY AND ENVIRONMENT
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 7期号:3 |
| 关键词 | Catalytic Transformation Cellulose Fractionation Humicellulose Ionic Liquids Lignin Lignocellulose Mechanism |
| ISSN号 | 2041-8396 |
| DOI | 10.1002/wene.284 |
| 文献子类 | Review |
| 英文摘要 | In biomass refinery, ionic liquids (ILs) enable more efficient conversion and higher product selectivity at milder conditions compared with conventional molecular solvents. Carbohydrates and lignin are the dominating components in biomass. The aim of this article is to update the recent progresses of ionic liquids-based catalytic systems for lignocellulosic biomass conversions based on the published works mostly in the last 5 years. Mechanistic understanding of the catalytic processes in converting biomass to renewable chemicals and fuels is critically important for the design of superior catalysts. Apart from theoretical approaches, two recently developed characterization techniques, in situ far infrared spectroscopy and two-dimensional nuclear magnetic resonance have been applied in the molecular level understanding of both catalysts and catalyzed reactions during biomass conversions in ILs. The major challenges and opportunities involved in the large-scale production of biomass platform chemicals are also discussed. |
| WOS关键词 | LIGNOCELLULOSIC BIOMASS ; 1-BUTYL-3-METHYLIMIDAZOLIUM CHLORIDE ; 1,4-BETA-GLYCOSIDIC BOND ; ENZYMATIC-HYDROLYSIS ; PLATFORM MOLECULES ; HYDROCARBON FUELS ; ORGANIC-SYNTHESIS ; METAL CHLORIDES ; EUCALYPTUS BARK ; MILD CONDITIONS |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000430399400003 |
| 出版者 | WILEY PERIODICALS, INC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169058]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Z. Conrad |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing, Peoples R China 2.Long Isl Univ Post, Dept Chem, Brookville, NY USA 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Cheng,Yang, Yiwen,Zhang, Z. Conrad. Advances in catalytic transformations of carbohydrates and lignin in ionic liquids and mechanistic studies[J]. WILEY INTERDISCIPLINARY REVIEWS-ENERGY AND ENVIRONMENT,2018,7(3). |
| APA | Zhang, Cheng,Yang, Yiwen,&Zhang, Z. Conrad.(2018).Advances in catalytic transformations of carbohydrates and lignin in ionic liquids and mechanistic studies.WILEY INTERDISCIPLINARY REVIEWS-ENERGY AND ENVIRONMENT,7(3). |
| MLA | Zhang, Cheng,et al."Advances in catalytic transformations of carbohydrates and lignin in ionic liquids and mechanistic studies".WILEY INTERDISCIPLINARY REVIEWS-ENERGY AND ENVIRONMENT 7.3(2018). |
入库方式： OAI收割
来源：大连化学物理研究所
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