Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes
文献类型：期刊论文
| 作者 | Yang, Xifa1,2; Li, Yunyun1,2; Kong, Lingheng1,2; Li, Xingwei2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2018-04-06 |
| 卷号 | 20期号:7页码:1957-1960 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.8b00497 |
| 文献子类 | Article |
| 英文摘要 | Rh(III)-catalyzed C-H activation of arenes and mild oxidative [4 + 2] annulative coupling with ketenes have been realized. The uniquely high reactivity of the C(3) of 2-phenylindoles was successfully utilized to facilitate the reductive elimination process, leading to efficient synthesis of cyclic products with a quaternary carbon stereocenter. |
| WOS关键词 | C-H ACTIVATION ; CYCLATIVE CAPTURE APPROACH ; RH-CATALYZED ANNULATIONS ; CARBON-HYDROGEN BONDS ; CARBOXYLIC-ACIDS ; N-METHOXYBENZAMIDES ; INTERNAL ALKYNES ; DIAZO-COMPOUNDS ; REGIOSELECTIVE SYNTHESIS ; OXIDATIVE ANNULATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000429886900062 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169148]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xifa,Li, Yunyun,Kong, Lingheng,et al. Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes[J]. ORGANIC LETTERS,2018,20(7):1957-1960. |
| APA | Yang, Xifa,Li, Yunyun,Kong, Lingheng,&Li, Xingwei.(2018).Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes.ORGANIC LETTERS,20(7),1957-1960. |
| MLA | Yang, Xifa,et al."Access to Quaternary Stereogenic Centers via Rhodium(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes".ORGANIC LETTERS 20.7(2018):1957-1960. |
入库方式： OAI收割
来源：大连化学物理研究所
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