Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO
文献类型：期刊论文
| 作者 | Li, Guosong1; Niu, Jingyang2; Gao, Shuang1; Wang, Lianyue1; Bie, Zhixing2; Shang, Sensen1 |
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2018-03-29 |
| 卷号 | 3期号:12页码:3386-3390 |
| 关键词 | Aerobic Oxidation Alcohols Copper Multi-functional Tempo |
| ISSN号 | 2365-6549 |
| DOI | 10.1002/slct.201800398 |
| 文献子类 | Article |
| 英文摘要 | A novel and easily accessible N-methylimidazole derived TEMPO as multi-functional molecule combining with commercially available copper(I) iodide and 4,4'-Di-tert-butyl-2,2'-dipyridyl afford a catalyst system that shows efficient activity for the oxidation of a broad scope of alcohols under air balloon at room temperature. The corresponding aldehydes and ketones were obtained in good to excellent yields. The procedure is readily amenable to scale up. The present catalytic system shows a high chemoselective oxidation of primary alcohols over secondary alcohols. Cu(II) active species generated in situ from Cu(I) is responsible for the oxidation of alcohols. |
| WOS关键词 | SECONDARY BENZYLIC ALCOHOLS ; ROOM-TEMPERATURE ; MOLECULAR-OXYGEN ; CARBONYL-COMPOUNDS ; PROPARGYLIC ALCOHOLS ; MILD CONDITIONS ; ALDEHYDES ; EFFICIENT ; KETONES ; SYSTEM |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000429418000004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169166]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gao, Shuang; Wang, Lianyue |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Henan Univ, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate Chem, Coll Chem & Chem Engn, Kaifeng 475004, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Guosong,Niu, Jingyang,Gao, Shuang,et al. Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO[J]. CHEMISTRYSELECT,2018,3(12):3386-3390. |
| APA | Li, Guosong,Niu, Jingyang,Gao, Shuang,Wang, Lianyue,Bie, Zhixing,&Shang, Sensen.(2018).Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO.CHEMISTRYSELECT,3(12),3386-3390. |
| MLA | Li, Guosong,et al."Cu-Catalyzed Aerobic Oxidation of Alcohols with a Multi-Functional NMI-TEMPO".CHEMISTRYSELECT 3.12(2018):3386-3390. |
入库方式： OAI收割
来源：大连化学物理研究所
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