A green route for methanol carbonylation
文献类型：期刊论文
| 作者 | Liu, Yong1,2; Ni, Youming1,2; Shi, Lei1,2; Liu, Hongchao1,2; Zhang, Wenna1,2,3; Zhu, Wenliang1,2; Liu, Zhongmin1,2 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2017-10-21 |
| 卷号 | 7期号:20页码:4818-4822 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c7cy01621b |
| 文献子类 | Article |
| 英文摘要 | Acetic acid is one of the most important bulk commodity chemicals and is currently manufactured by methanol carbonylation reactions with rhodium or iridium organometallic complexes and halide-containing promoters named Monsanto or BP Cativa T homogeneous processes, respectively. Developing a halide-free catalyst and a heterogeneous process for methanol carbonylation is of great importance and has recently attracted extensive research attention. Here, we report a green route for direct synthesis of acetic acid via vapor-phase carbonylation of methanol with a stable, selective, halide-free, and noble metal-free catalyst based on pyridine-modified H-mordenite zeolite. Methanol conversion and acetic acid selectivity can reach up to 100% and 95%, respectively. Only little deactivation is observed during the 145 hour reaction. |
| WOS关键词 | DIMETHYL ETHER CARBONYLATION ; SOLID ACID CATALYSTS ; METHYL ACETATE ; SELECTIVE CARBONYLATION ; MORDENITE ZEOLITE ; SPECIFICITY ; PROMOTION ; MECHANISM ; CHANNELS ; SITES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000413192900023 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169220]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhu, Wenliang; Liu, Zhongmin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian, PR, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yong,Ni, Youming,Shi, Lei,et al. A green route for methanol carbonylation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7(20):4818-4822. |
| APA | Liu, Yong.,Ni, Youming.,Shi, Lei.,Liu, Hongchao.,Zhang, Wenna.,...&Liu, Zhongmin.(2017).A green route for methanol carbonylation.CATALYSIS SCIENCE & TECHNOLOGY,7(20),4818-4822. |
| MLA | Liu, Yong,et al."A green route for methanol carbonylation".CATALYSIS SCIENCE & TECHNOLOGY 7.20(2017):4818-4822. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。