Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion
文献类型：期刊论文
| 作者 | Guo, Ang2; Dong, Yu-Bin1; Yao, Bing-Jian1; Ding, Luo-Gang1; Li, Fei1; Li, Jiang-Tao1; Fu, Qi-Juan1; Ban, Yujie2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-11-08 |
| 卷号 | 9期号:44页码:38919-38930 |
| 关键词 | Mofs Gas Separation Cross-linked Membrane Catalytic Cycloaddition Polyurethane Ionic Liquid |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.7b12697 |
| 文献子类 | Article |
| 英文摘要 | Carbon dioxide capture and transformation are of great importance to make cuts in greenhouse gas emissions. Nanometal-organic frameworks (NMOFs) could serve as ideal fillers for polymer membranes owing to their structural diversity and regulable micro-environment of the nanocage. Herein, a bifunctional, robust, and chemically cross-linked NMOF-based membrane was successfully constructed by the postsynthetic polymerization of imidazolium-based ionic liquid (IL)-decorated UiO-66 type nanoparticles (NPs) and the isocyanate-terminated polyurethane oligomer under mild conditions. The IL-modified MOF-polymer membranes exhibit a highly selective adsorption for CO2 over N-2 and CH4. In addition, the obtained membrane can also be a highly active heterogeneous catalyst for CO2 transformation by cycloaddition with epoxide under an ambient pressure. |
| WOS关键词 | MIXED-MATRIX MEMBRANES ; METAL-ORGANIC FRAMEWORK ; CARBON-DIOXIDE CAPTURE ; CO2/CH4 SEPARATION ; GAS SEPARATION ; THIN-FILMS ; POLYIMIDE ; CYCLOADDITION ; ADSORPTION ; FUNCTIONALIZATION |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000415140800081 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169250]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Dong, Yu-Bin; Yao, Bing-Jian |
| 作者单位 | 1.Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Coll Chem Chem Engn & Mat Sci, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Ang,Dong, Yu-Bin,Yao, Bing-Jian,et al. Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(44):38919-38930. |
| APA | Guo, Ang.,Dong, Yu-Bin.,Yao, Bing-Jian.,Ding, Luo-Gang.,Li, Fei.,...&Ban, Yujie.(2017).Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion.ACS APPLIED MATERIALS & INTERFACES,9(44),38919-38930. |
| MLA | Guo, Ang,et al."Chemically Cross-Linked MOF Membrane Generated from Imidazolium-Based Ionic Liquid-Decorated UiO-66 Type NMOF and Its Application toward CO2 Separation and Conversion".ACS APPLIED MATERIALS & INTERFACES 9.44(2017):38919-38930. |
入库方式： OAI收割
来源：大连化学物理研究所
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