Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation
文献类型：期刊论文
| 作者 | Song, Guoyong1; Li, Xingwei2; Chen, Xiaohong1,2; Zheng, Guangfan2; Li, Yunyun2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-11-17 |
| 卷号 | 19期号:22页码:6184-6187 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/acs.orglett.7b03099 |
| 文献子类 | Article |
| 英文摘要 | A Rh(III)-catalyzed site-selective C-H activation of C(3)-functionalized indoles in a coupling with diazo esters has been realized with carbonyl as a weakly coordinating group. The coupling selectivity is dictated by the temperature and additives, affording either C4-alkylated indoles or C2-annulated lactones in moderate to excellent efficiency. |
| WOS关键词 | C-H ACTIVATION ; N-PIVALOYLINDOLES ; BOND ACTIVATION ; RH(III)-CATALYZED SYNTHESIS ; COMPOUNDS ACCESS ; MILD CONDITIONS ; DIRECTING GROUP ; OXYGEN-ATOM ; FUNCTIONALIZATION ; ARYLATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000416204300039 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169280]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Song, Guoyong; Li, Xingwei |
| 作者单位 | 1.Beijing Forestry Univ, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Guoyong,Li, Xingwei,Chen, Xiaohong,et al. Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation[J]. ORGANIC LETTERS,2017,19(22):6184-6187. |
| APA | Song, Guoyong,Li, Xingwei,Chen, Xiaohong,Zheng, Guangfan,&Li, Yunyun.(2017).Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation.ORGANIC LETTERS,19(22),6184-6187. |
| MLA | Song, Guoyong,et al."Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation".ORGANIC LETTERS 19.22(2017):6184-6187. |
入库方式： OAI收割
来源：大连化学物理研究所
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