Sn-119 Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance
文献类型:期刊论文
作者 | Veerappan, Ganapathy3; Wang, Junhu1; Sundaram, Ganeshraja Ayyakannu1; Yang, Minghui1; Nomura, Kiyoshi2; Maniarasu, Suresh3; Liu, Tao4 |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
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出版日期 | 2017-03-30 |
卷号 | 121期号:12页码:6662-6673 |
ISSN号 | 1932-7447 |
DOI | 10.1021/acs.jpcc.6b12397 |
文献子类 | Article |
英文摘要 | Hierarchical tin-doped titania (ST) and tin- and nitrogencodoped titania (SNT) microspheres were prepared by a hydrothermal method and nitriding treatment, in particular, SNT-enhanced visible light photocatalytic activity for the degradation of rhodamine B in aqueous solution and room-temperature ferromagnetism (RTFM). We initiated the photovoltaic study of ST and SNT microspheres to confirm the photovoltaic properties of perovskite solar cell (PSC) applications. The SNT microspheres exhibited relatively large saturation magnetization and high photocatalytic activity. To clarify the enhancement of the photo activity, the prepared samples were characterized by Sn-119 Mossbauer spectrometry under external magnetic fields. The broadened peaks of ST and SNT microspheres were decomposed into a doublet and a sextet under an external magnetic field because the samples showed weak ferromagnetism, although these samples are composed of nonmagnetic components. It is noteworthy that ST and SNT microspheres exhibits oxygen vacancies and defect-induced magnetism. The results signify the clear details of the RTFM and the photocatalytic activity of hierarchical ST and SNT microspheres. |
WOS关键词 | VISIBLE-LIGHT PHOTOCATALYSIS ; ROOM-TEMPERATURE FERROMAGNETISM ; DOPED TIO2 ; SN ; ANATASE ; TITANIA ; METAL ; FILMS ; NANOPARTICLES ; NANOCRYSTALS |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000398247500028 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169304] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Wang, Junhu |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China 2.Tokyo Univ Sci, Photocatalysis Int Res Ctr, Noda, Chiba 2788510, Japan 3.Int Adv Res Ctr Powder Met & New Mat, Ctr Solar Energy Mat, Hyderabad 500005, Andhra Pradesh, India 4.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China |
推荐引用方式 GB/T 7714 | Veerappan, Ganapathy,Wang, Junhu,Sundaram, Ganeshraja Ayyakannu,et al. Sn-119 Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2017,121(12):6662-6673. |
APA | Veerappan, Ganapathy.,Wang, Junhu.,Sundaram, Ganeshraja Ayyakannu.,Yang, Minghui.,Nomura, Kiyoshi.,...&Liu, Tao.(2017).Sn-119 Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance.JOURNAL OF PHYSICAL CHEMISTRY C,121(12),6662-6673. |
MLA | Veerappan, Ganapathy,et al."Sn-119 Mossbauer and Ferromagnetic Studies on Hierarchical Tin- and Nitrogen-Codoped TiO2 Microspheres with Efficient Photocatalytic Performance".JOURNAL OF PHYSICAL CHEMISTRY C 121.12(2017):6662-6673. |
入库方式: OAI收割
来源:大连化学物理研究所
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