A cost-effective nanoporous ultrathin film electrode based on nanoporous gold/IrO2 composite for proton exchange membrane water electrolysis
文献类型：期刊论文
| 作者 | Zhang, Hongjie1,2; Yi, Baolian1; Zeng, Yachao1,2; Guo, Xiaoqian1,2; Shao, Zhigang1; Yu, Hongmei1; Song, Wei1,2; Wang, Zhiqiang1,2 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2017-02-28 |
| 卷号 | 342页码:947-955 |
| 关键词 | Proton Exchange Membrane Water Electrolysis Nanoporous Gold Nanoporous Ultrathin Film Electrode Membrane Electrode Assembly Ultralow Iridium Loading |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2017.01.021 |
| 文献子类 | Article |
| 英文摘要 | A cost-effective nanoporous ultrathin film (NPUF) electrode based on nanoporous gold (NPG)/IrO2 composite has been constructed for proton exchange membrane (PEM) water electrolysis. The electrode was fabricated by integrating IrO2 nanoparticles into NPG through a facile dealloying and thermal decomposition method. The NPUF electrode is featured in its 3D interconnected nanoporosity and ultrathin thickness. The nanoporous ultrathin architecture is binder-free and beneficial for improving electrochemical active surface area, enhancing mass transport and facilitating releasing of oxygen produced during water electrolysis. Serving as anode, a single cell performance of 1.728 V (@ 2 A cm(-2)) has been achieved by NPUF electrode with a loading of IrO2 and Au at 86.43 and 100.0 mu g cm(-2) respectively, the electrolysis voltage is 58 mV lower than that.of conventional electrode with an Ir loading an order of magnitude higher. The electrolysis voltage kept relatively constant up to 300 h (@250 mA cm(-2)) during the course of durability test, manifesting that NPUF electrode is promising for gas evolution. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | CATALYST-COATED MEMBRANE ; SOLID POLYMER ELECTROLYTE ; OXYGEN EVOLUTION CATALYSTS ; FUEL-CELLS ; OXIDE ELECTROCATALYSTS ; HIGH-PERFORMANCE ; IMPEDANCE SPECTROSCOPY ; SURFACE-COMPOSITION ; GOLD ; CONDUCTIVITY |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000396186300108 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169334]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Shao, Zhigang; Yu, Hongmei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Syst & Engn Lab, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hongjie,Yi, Baolian,Zeng, Yachao,et al. A cost-effective nanoporous ultrathin film electrode based on nanoporous gold/IrO2 composite for proton exchange membrane water electrolysis[J]. JOURNAL OF POWER SOURCES,2017,342:947-955. |
| APA | Zhang, Hongjie.,Yi, Baolian.,Zeng, Yachao.,Guo, Xiaoqian.,Shao, Zhigang.,...&Wang, Zhiqiang.(2017).A cost-effective nanoporous ultrathin film electrode based on nanoporous gold/IrO2 composite for proton exchange membrane water electrolysis.JOURNAL OF POWER SOURCES,342,947-955. |
| MLA | Zhang, Hongjie,et al."A cost-effective nanoporous ultrathin film electrode based on nanoporous gold/IrO2 composite for proton exchange membrane water electrolysis".JOURNAL OF POWER SOURCES 342(2017):947-955. |
入库方式： OAI收割
来源：大连化学物理研究所
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