Size-controlled synthesis of hierarchical ferrierite zeolite and its catalytic application in 1-butene skeletal isomerization
文献类型:期刊论文
作者 | Li, Xiujie1; Chu, Weifeng1,2; Zhu, Xiangxue1; Xie, Sujuan1; Guo, Ce1,2; Liu, Shenglin1; Chen, Fucun1; Xu, Longya1 |
刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
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出版日期 | 2017-03-01 |
卷号 | 240页码:189-196 |
关键词 | Hierarchical Ferrierite Nano-zeolite Aggregates 1-butene Skeletal Isomerization |
ISSN号 | 1387-1811 |
DOI | 10.1016/j.micromeso.2016.11.015 |
文献子类 | Article |
英文摘要 | Nano-ferrierite zeolite aggregates with hierarchical porosity were successfully prepared by using pyrrolidine as sole organic structure-directing agent. SEM and TEM images revealed that nano-sized crystals (40-60 nm) stacked together loosely to form irregular clusters. Influence of crystallization temperature and initial gel compositions (pyrrolidine content, alkalinity, water content) on the synthesis of ferrierite zeolite were investigated in detail. Low crystallization temperature and high alkalinity were beneficial to form nano-ferrierite zeolite aggregates with high hierarchical porosity (total pore volume: 0.461 cm(3)/g). Compared with commercialized ferrierite zeolite, hierarchical nano-ferrierite aggregates showed better catalytic stability and product selectivity in the 1-butene skeletal isomerization reaction. (C) 2016 Elsevier Inc. All rights reserved. |
WOS关键词 | FER ZEOLITE ; SYSTEM ; ACID ; PYRIDINE ; ZSM-5 ; NMR |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
WOS记录号 | WOS:000395604600023 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169356] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Li, Xiujie; Xu, Longya |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xiujie,Chu, Weifeng,Zhu, Xiangxue,et al. Size-controlled synthesis of hierarchical ferrierite zeolite and its catalytic application in 1-butene skeletal isomerization[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2017,240:189-196. |
APA | Li, Xiujie.,Chu, Weifeng.,Zhu, Xiangxue.,Xie, Sujuan.,Guo, Ce.,...&Xu, Longya.(2017).Size-controlled synthesis of hierarchical ferrierite zeolite and its catalytic application in 1-butene skeletal isomerization.MICROPOROUS AND MESOPOROUS MATERIALS,240,189-196. |
MLA | Li, Xiujie,et al."Size-controlled synthesis of hierarchical ferrierite zeolite and its catalytic application in 1-butene skeletal isomerization".MICROPOROUS AND MESOPOROUS MATERIALS 240(2017):189-196. |
入库方式: OAI收割
来源:大连化学物理研究所
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