Pd-Containing Core/Pt-Based Shell Structured Electrocatalysts
文献类型：期刊论文
| 作者 | Song Yu-Jiang1; Liu Hui-Yuan1,2,3; Lu Yang1; Li Huan-Qiao2 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2017-02-15 |
| 卷号 | 33期号:2页码:283-294 |
| 关键词 | Proton Exchange Membrane Fuel Cell Core-shell Structured Electrocatalyst Oxygen Reduction Reaction Formic Acid Oxidation Reaction Durability |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB201611071 |
| 文献子类 | Article |
| 英文摘要 | Fuel cell vehicles (FCVs) have been a burgeoning industry in China, and are currently on the verge of widespread commercialization. The platinum-based electrocatalyst is one of the key materials in proton exchange membrane fuel cells (PEMFCs). The relatively low activity and durability, and high cost of the electrocatalyst impede the further development of PEMFCs as a clean energy technology. It has been widely anticipated that core-shell structured low-platinum electrocatalysts with high performance toward oxygen reduction reaction (ORR) will eventually resolve this bottleneck issue. Regardless of significant progress, there are still many remaining issues, such as complicated synthesis route, the large sizes of core materials like Pd, and lack of macroscopic characterization of the core-shell structures. Herein, we introduce two new synthetic methods (one pot synthesis and regioselective atomic layer deposition (ALD) combined with a wet chemical method) for the fabrication of core-shell structured Pd3Au@Pt/C electrocatalysts with high ORR performance. These two synthetic approaches allow us to well control the diameter of the core nanoparticle to around 5 nm. Cyclic voltammetry (CV) and formic acid oxidation reaction (FAOR) were found to be suitable for investigating the integrity of the Pt shell on the core particles. This work represents a new avenue for the macroscopic characterization of the core-shell structured electrocatalysts with Pd or Pd alloy as the core material. |
| WOS关键词 | OXYGEN REDUCTION REACTION ; ATOMIC LAYER DEPOSITION ; SURFACE ELECTRONIC-STRUCTURE ; PEM FUEL-CELLS ; STRAIN CONTROL ; NANOPARTICLES ; PLATINUM ; CATALYSTS ; MONOLAYER ; STABILITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000394735200002 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169362]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Song Yu-Jiang |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song Yu-Jiang,Liu Hui-Yuan,Lu Yang,et al. Pd-Containing Core/Pt-Based Shell Structured Electrocatalysts[J]. ACTA PHYSICO-CHIMICA SINICA,2017,33(2):283-294. |
| APA | Song Yu-Jiang,Liu Hui-Yuan,Lu Yang,&Li Huan-Qiao.(2017).Pd-Containing Core/Pt-Based Shell Structured Electrocatalysts.ACTA PHYSICO-CHIMICA SINICA,33(2),283-294. |
| MLA | Song Yu-Jiang,et al."Pd-Containing Core/Pt-Based Shell Structured Electrocatalysts".ACTA PHYSICO-CHIMICA SINICA 33.2(2017):283-294. |
入库方式： OAI收割
来源：大连化学物理研究所
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