Synthesis, characterization, thermal, electrical and magnetic properties of polyaniline composites with rare earth gadolinium coordination complex
文献类型：期刊论文
| 作者 | Wang, Shaoxu1; Zhang, Youyou1; Tan, Zhicheng2; Wang, Siyu1; Li, Yini1 |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 28期号:3页码:411-420 |
| 关键词 | Pani/ Gd Composite Thermal Stability Electrochemical Performance Magnetic Properties |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.3913 |
| 文献子类 | Article |
| 英文摘要 | Novel polyaniline/gadolinium (PANI/Gd) composites were successfully synthesized by in-situ polymerization at the presence of rare earth Gd coordination complex and D-tartaric acid (an a dopant). It is rarely to find the studies on related field to add rare earth Gd coordination complex as fillers. Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to examine the structure and surface appearance characterization of materials. The thermal stability performance of composites was investigated by thermogravimetry and derivative thermogravimetry (TG-DTG). Electrochemical performance was measured by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge test. The magnetic property was investigated by physical property measurement system (PPMS). The structure and surface appearance characterization and the magnetic properties jointly demonstrate the polymerization of rare earth Gd coordination complex and PANI-D-tartrate (DTA) not only simple physical mixing but also chemical mixing. TG-DTG analysis suggests that thermal stability of PANI/Gd composites is higher than that of PANI-DTA. Electrochemical performance tests and SEM indicate that the composite (PANI/Gd=3.3:1,mass ratio) has the most regular morphology and best specific capacitance. The magnetization of the composite (PANI/Gd=3.3:1,mass ratio)is evidently smaller compared with PANI-DTA and rare earth Gd coordination complex. Copyright (c) 2016 John Wiley & Sons, Ltd. |
| WOS关键词 | ORGANIC-INORGANIC NANOCOMPOSITES ; MICROWAVE-ABSORPTION ; OXIDE COMPOSITES ; ELECTRODE MATERIALS ; NANOPARTICLES ; STABILITY ; ATMOSPHERE |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000394691200015 |
| 出版者 | WILEY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169372]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Shaoxu |
| 作者单位 | 1.Dalian Jiaotong Univ, Coll Environm Sci & Engn, Dalian 116028, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shaoxu,Zhang, Youyou,Tan, Zhicheng,et al. Synthesis, characterization, thermal, electrical and magnetic properties of polyaniline composites with rare earth gadolinium coordination complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2017,28(3):411-420. |
| APA | Wang, Shaoxu,Zhang, Youyou,Tan, Zhicheng,Wang, Siyu,&Li, Yini.(2017).Synthesis, characterization, thermal, electrical and magnetic properties of polyaniline composites with rare earth gadolinium coordination complex.POLYMERS FOR ADVANCED TECHNOLOGIES,28(3),411-420. |
| MLA | Wang, Shaoxu,et al."Synthesis, characterization, thermal, electrical and magnetic properties of polyaniline composites with rare earth gadolinium coordination complex".POLYMERS FOR ADVANCED TECHNOLOGIES 28.3(2017):411-420. |
入库方式： OAI收割
来源：大连化学物理研究所
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