The porous membrane with tunable performance for vanadium flow battery: The effect of charge
文献类型：期刊论文
| 作者 | Yuan, Zhizhang1,3; Lu, Wenjing1,3; Li, Xianfeng1,2; Zhang, Huamin1,2; Zhao, Yuyue1,3 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2017-02-28 |
| 卷号 | 342页码:327-334 |
| 关键词 | Vanadium Flow Battery Porous Membrane Solvent-responsive Layer-by-layer (Sr-lbl) Assemble Method Surface Charge |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2016.12.058 |
| 文献子类 | Article |
| 英文摘要 | Porous membranes with different charge on the surface and internal pore walls are prepared via the solvent-responsive layer-by-layer (SR-LBL) method. The effect of charge on the transport properties of different ions through the membranes is investigated in detail. The charge property of prepared membranes is tuned by assembling different charged polyelectrolytes (PEs) on the pore walls and the surface of the porous membranes. The results show that in a vanadium flow battery (VFB), the PE layers assembled on the surfaces (including pore walls) are capable to construct excellent ion transport channels to increase proton conductivity and to tune the ion selectivity via Donnan exclusion effect. Compared with the porous membrane with negative charges (7 bilayers), a VFB single cell assembled with a positively charged membrane (7.5 bilayers) yields a higher coulombic efficiency (98%). The water and ion transfer behavior exhibits a similar tendency. In the negative half-cell, the amount of V3+ gradually increases as cycles proceed and the amount of V2+ stays at a low and stable level. In the positive half-cell, the amount of VO2+ decreases; while VO2+ is accumulated. The imbalance of vanadium ions at both sides induces the discharge capacity fade. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | BROAD TEMPERATURE ADAPTABILITY ; RESEARCH-AND-DEVELOPMENT ; ETHER KETONE) MEMBRANES ; CONDUCTIVE MEMBRANES ; CAPACITY DECAY ; TRANSPORT ; LAYER ; SELECTIVITY ; SEPARATOR ; MECHANISM |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000396186300037 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169390]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xianfeng; Zhang, Huamin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Zhongshan Rd 457, Dalian 116023, Peoples R China 2.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Zhizhang,Lu, Wenjing,Li, Xianfeng,et al. The porous membrane with tunable performance for vanadium flow battery: The effect of charge[J]. JOURNAL OF POWER SOURCES,2017,342:327-334. |
| APA | Yuan, Zhizhang,Lu, Wenjing,Li, Xianfeng,Zhang, Huamin,&Zhao, Yuyue.(2017).The porous membrane with tunable performance for vanadium flow battery: The effect of charge.JOURNAL OF POWER SOURCES,342,327-334. |
| MLA | Yuan, Zhizhang,et al."The porous membrane with tunable performance for vanadium flow battery: The effect of charge".JOURNAL OF POWER SOURCES 342(2017):327-334. |
入库方式： OAI收割
来源：大连化学物理研究所
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