Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane
文献类型：期刊论文
| 作者 | Chen, Ping1; Zhang, Miao1,2; Liu, Lin1; He, Teng1; Li, Zhao1,2; Wu, Guotao1 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2017-02-16 |
| 卷号 | 12期号:4页码:470-475 |
| 关键词 | Covalent Triazine Framework Hydrolysis Microporous Materials Mesoporous Materials Template Synthesis |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201601631 |
| 文献子类 | Article |
| 英文摘要 | Significant progress has been made on the synthesis and application of mesoporous g-alumina. To date, little attention has been paid to the synthesis of microporous crystalline alumina. Here, fabrication of microporous crystalline g-alumina using a microporous covalent triazine framework (CTF-1) as a template is described. Microporous crystalline g-alumina with a micro-meso binary pore system was replicated by infiltration of aluminum nitrate into the micropores of the CTF-1 template through a NH3/water-vapor-induced internal hydrolysis method, followed by thermal treatment, and subsequent removal of the CTF-1 template with a 30% H2O2 aqueous solution. The obtained crystalline g-alumina material exhibits a large surface area (349 m(2)g(-1)) with micropore distribution centered at about 1.27 nm. Ru supported on microporous gamma-Al2O3 can be employed as catalyst for hydrolytic dehydrogenation of ammonia borane, and it exhibits high catalytic activity and good durability. This finding provides a new benchmark for preparing well-defined crystalline microporous alumina materials by a template method, which can be applied in a wide range of fields. |
| WOS关键词 | CHEMICAL HYDROGEN STORAGE ; METAL-ORGANIC FRAMEWORK ; NONIONIC SURFACTANTS ; MESOPOROUS MATERIALS ; ROOM-TEMPERATURE ; FACILE SYNTHESIS ; ALUMINA ; OXIDES ; DEHYDROGENATION ; CAPACITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000397025000014 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169408]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Lin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Ping,Zhang, Miao,Liu, Lin,et al. Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(4):470-475. |
| APA | Chen, Ping,Zhang, Miao,Liu, Lin,He, Teng,Li, Zhao,&Wu, Guotao.(2017).Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane.CHEMISTRY-AN ASIAN JOURNAL,12(4),470-475. |
| MLA | Chen, Ping,et al."Microporous Crystalline gamma-Al2O3 Replicated from Microporous Covalent Triazine Framework and Its Application as Support for Catalytic Hydrolysis of Ammonia Borane".CHEMISTRY-AN ASIAN JOURNAL 12.4(2017):470-475. |
入库方式： OAI收割
来源：大连化学物理研究所
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