Synthesis of Renewable Triketones, Diketones, and Jet-Fuel Range Cycloalkanes with 5-Hydroxymethylfurfural and Ketones
文献类型：期刊论文
| 作者 | Wang, Wentao1; Sheng, Xueru1,2; Wang, Aiqin1,3; Cong, Yu1; Zhang, Tao1,3; Wang, Xiaodong1; Li, Shanshan1,2; Chen, Fang1,2; Li, Ning1,3 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2017-02-22 |
| 卷号 | 10期号:4页码:711-719 |
| 关键词 | Aqueous-phase Hydrogenation Diketones Jet Fuel Lignocellulose Triketones |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201601727 |
| 文献子类 | Article |
| 英文摘要 | A series of renewable C-9-C-12 triketones with repeating [COCH2CH2] units were synthesized in high carbon yields (ca. 90%) by the aqueous-phase hydrogenation of the aldol-condensation products of 5-hydroxylmethylfurfural (HMF) and ketones over an Au/TiO2 catalyst. Compared with the reported routes, this new route has many advantages such as being environmentally friendly, having fewer steps, using a cheaper and reusable catalyst, etc. The triketones as obtained can be used as feedstocks in the production of conducting or semi-conducting polymers. Through a solvent-free intramolecular aldol condensation over solid-base catalysts, the triketones were selectively converted to diketones, which can be used as intermediates in the synthesis of useful chemicals or polymers. As another application, the tri-and diketones can also be utilized as precursors for the synthesis of jet-fuel range branched cycloalkanes with low freezing points (224-248 K) and high densities (ca. 0.81 gmL(-1)). |
| WOS关键词 | CATALYTIC FAST PYROLYSIS ; METHYL ISOBUTYL KETONE ; HIGH-QUALITY DIESEL ; TRANSPORTATION FUELS ; LIQUID ALKANES ; AQUEOUS-PHASE ; BIO-OIL ; BIOMASS ; CONVERSION ; CELLULOSE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000397006500010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169412]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Ning |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat, iChEM, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Wentao,Sheng, Xueru,Wang, Aiqin,et al. Synthesis of Renewable Triketones, Diketones, and Jet-Fuel Range Cycloalkanes with 5-Hydroxymethylfurfural and Ketones[J]. CHEMSUSCHEM,2017,10(4):711-719. |
| APA | Wang, Wentao.,Sheng, Xueru.,Wang, Aiqin.,Cong, Yu.,Zhang, Tao.,...&Li, Ning.(2017).Synthesis of Renewable Triketones, Diketones, and Jet-Fuel Range Cycloalkanes with 5-Hydroxymethylfurfural and Ketones.CHEMSUSCHEM,10(4),711-719. |
| MLA | Wang, Wentao,et al."Synthesis of Renewable Triketones, Diketones, and Jet-Fuel Range Cycloalkanes with 5-Hydroxymethylfurfural and Ketones".CHEMSUSCHEM 10.4(2017):711-719. |
入库方式： OAI收割
来源：大连化学物理研究所
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