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In situ Growth of Phase-Controlled Nickel Sulfide Nanostructures on Reduced Graphene Oxide Nanosheets : A Improved Cost-effective Catalyst for 4-Nitrophenol Reduction

文献类型:期刊论文

作者Prakash, Natarajan1; Hayakawa, Yasuhiro1,3; Karthikeyan, Rajan1,2; Thangaraju, Dheivasigamani3; Arivanandhan, Mukannan4
刊名CHEMISTRYSELECT
出版日期2017-02-01
卷号2期号:6页码:2187-2196
ISSN号2365-6549
DOI10.1002/slct.201601519
文献子类Article
英文摘要Reduced graphene oxide (rGO)-functionalized nickel sulfide nanoparticles were synthesized using a temperature-controlled injection method. Syntheses were carried out in single (oleylamine) and mixed (oleylamine, oleic acid, and octadecene) solvents. Phase-controlled NiS, NiS2, or Ni3S4 nanocrystals were decorated on rGO sheets through the single-step temperaturecontrolled injection processes. Problems with the synthesis of rGO/nickel sulfide yielding mixed phases were overcome by adjusting the solvent mixture and source concentrations. X-ray diffraction and transmission electron microscopy were used to study the crystal structures and phases of nickel sulfide on the rGO sheets. The catalytic performances of rGO/nickel sulfide structures containing different nickel sulfide phases were analyzed by measuring the degradation rate of 4-nitrophenol. Catalytic activity of as synthesized rGO/NiS, rGO/NiS2 and rGO/Ni3S4 were higher activity than pure NiS, among them rGO/NiS was showed better activity than those of rGO/NiS2 and rGO/Ni3S4.
WOS关键词GREEN SYNTHESIS ; DOPED GRAPHENE ; FACILE ; SUPERCAPACITORS ; NANOPARTICLES ; NANOCRYSTALS ; NANOCOMPOSITES ; DEGRADATION ; PERFORMANCE ; COMPOSITES
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000395534600022
出版者WILEY-V C H VERLAG GMBH
源URL[http://cas-ir.dicp.ac.cn/handle/321008/169466]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Hayakawa, Yasuhiro; Karthikeyan, Rajan
作者单位1.Shizuoka Univ, Grad Sch Sci & Technol, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328011, Japan
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Shizuoka Univ, Elect Res Inst, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328011, Japan
4.Anna Univ, Ctr Nanosci & Technol, Madras 600025, Tamil Nadu, India
推荐引用方式
GB/T 7714
Prakash, Natarajan,Hayakawa, Yasuhiro,Karthikeyan, Rajan,et al. In situ Growth of Phase-Controlled Nickel Sulfide Nanostructures on Reduced Graphene Oxide Nanosheets : A Improved Cost-effective Catalyst for 4-Nitrophenol Reduction[J]. CHEMISTRYSELECT,2017,2(6):2187-2196.
APA Prakash, Natarajan,Hayakawa, Yasuhiro,Karthikeyan, Rajan,Thangaraju, Dheivasigamani,&Arivanandhan, Mukannan.(2017).In situ Growth of Phase-Controlled Nickel Sulfide Nanostructures on Reduced Graphene Oxide Nanosheets : A Improved Cost-effective Catalyst for 4-Nitrophenol Reduction.CHEMISTRYSELECT,2(6),2187-2196.
MLA Prakash, Natarajan,et al."In situ Growth of Phase-Controlled Nickel Sulfide Nanostructures on Reduced Graphene Oxide Nanosheets : A Improved Cost-effective Catalyst for 4-Nitrophenol Reduction".CHEMISTRYSELECT 2.6(2017):2187-2196.

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来源:大连化学物理研究所

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