Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx
文献类型：期刊论文
| 作者 | Zhang, Tao1; Zhao, Xiaochen1; Wang, Jia1,3; Yang, Man1,2; Lei, Nian1,2; Li, Lin1; Hou, Baolin1; Miao, Shu1; Pan, Xiaoli1; Wang, Aiqin1 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2017-03-09 |
| 卷号 | 10期号:5页码:819-824 |
| 关键词 | Au Promotion Frustrated Lewism Pairs Glycerol Hydrogenolysis 1 3-propanediol |
| ISSN号 | 1864-5631 |
| DOI | 10.1002/cssc.201601503 |
| 文献子类 | Article |
| 英文摘要 | A highly dispersed Au and Pt catalyst supported on WOx was developed for high performance in the selective hydrogenolysis of glycerol to 1,3-propanediol (1,3-PD) under very mild reaction conditions (81.4% glycerol conversion, 51.6% 1,3-PD selectivity at 413 K, 1 MPa H-2). The highly dispersed Au decreased the original surface Lewis-acid sites on Pt/WOx but greatly increased its in situ generated Bronsted-acid sites with the assistance of H2 through the formation of frustrated Lewis pairs. These in situ formed and spatially separated pairs of H+ and H+ function as the active sites in glycerol conversion to 1,3-PD. |
| WOS关键词 | IR-RE CATALYSTS ; CHEMOSELECTIVE HYDROGENATION ; BIMETALLIC CATALYSTS ; TUNGSTEN-OXIDE ; CHEMICALS ; HYDRODEOXYGENATION ; TEMPERATURE ; ACTIVATION ; CONVERSION ; SURFACES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000398182300001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169470]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Tao; Wang, Aiqin |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Northwest A&F Univ, Coll Forestry, 3 Taicheng Rd, Yangling 712100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Tao,Zhao, Xiaochen,Wang, Jia,et al. Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx[J]. CHEMSUSCHEM,2017,10(5):819-824. |
| APA | Zhang, Tao.,Zhao, Xiaochen.,Wang, Jia.,Yang, Man.,Lei, Nian.,...&Wang, Aiqin.(2017).Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx.CHEMSUSCHEM,10(5),819-824. |
| MLA | Zhang, Tao,et al."Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WOx".CHEMSUSCHEM 10.5(2017):819-824. |
入库方式： OAI收割
来源：大连化学物理研究所
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