Fluorene-Based Two-Dimensional Covalent Organic Framework with Thermoelectric Properties through Doping
文献类型：期刊论文
| 作者 | Xu, Jingkun2; Jiang, Fengxing2; Wang, Liangying1; Dong, Bin1,3; Ge, Rile1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 9期号:8页码:7108-7114 |
| 关键词 | Covalent Organic Frameworks Fluorene Units Iodine Doping Electrical Conductivity Thermoelectric Properties |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.6b14916 |
| 文献子类 | Article |
| 英文摘要 | Organic semiconductors have great potential as flexible thermoelectric materials. A fluorene-based covalent organic framework (FL-COF-1) was designed with the aim of creating an enhanced pi-pi interaction among the crystalline backbones. By the introduction of fluorene units into the frameworks, the FL-COF-1 had high thermal stability with a BET surface area over 1300 m(2) g(-1). The open frameworks were favorable for doping with iodine and followed with the improved charge carrier mobility. The compressed pellet of I-2@FL-COF-1 exhibited a high Seebeck coefficient of 2450 mu V K-1 and power factor of 0.063 mu W m(-1) K-2 at room temperature, giving the first example of COFs' potential application as thermoelectric materials. |
| WOS关键词 | SEEBECK COEFFICIENT ; HYDROGEN-BONDS ; POWER FACTOR ; THIN-FILMS ; PERFORMANCE ; CRYSTALLINE ; SEMICONDUCTORS ; ENHANCEMENT ; POLYMERS ; PEDOTPSS |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000395494200047 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169478]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xu, Jingkun; Dong, Bin |
| 作者单位 | 1.Dalian Inst Chem Phys, Chinese Acad Sci, Dalian 116023, Peoples R China 2.Jiangxi Sci & Technol Normal Univ, Coll Pharm, Nanchang 330013, Jiangxi, Peoples R China 3.China Univ Min & Technol, Coll Chem Engn, Xuzhou 221116, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jingkun,Jiang, Fengxing,Wang, Liangying,et al. Fluorene-Based Two-Dimensional Covalent Organic Framework with Thermoelectric Properties through Doping[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(8):7108-7114. |
| APA | Xu, Jingkun,Jiang, Fengxing,Wang, Liangying,Dong, Bin,&Ge, Rile.(2017).Fluorene-Based Two-Dimensional Covalent Organic Framework with Thermoelectric Properties through Doping.ACS APPLIED MATERIALS & INTERFACES,9(8),7108-7114. |
| MLA | Xu, Jingkun,et al."Fluorene-Based Two-Dimensional Covalent Organic Framework with Thermoelectric Properties through Doping".ACS APPLIED MATERIALS & INTERFACES 9.8(2017):7108-7114. |
入库方式： OAI收割
来源：大连化学物理研究所
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