Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite
文献类型:期刊论文
作者 | Xin, Qin3; Liu, Jiaxu1,2; Wang, Jilei1,2; Zhou, Wei1,2; Miao, Cuilan1,2; Xiong, Guang1,2; Guo, Hongchen1,2 |
刊名 | CHINESE JOURNAL OF CATALYSIS
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出版日期 | 2017 |
卷号 | 38期号:1页码:13-19 |
关键词 | Operando Db-ftir Gas-phase Molecular Vibration Spectroscopy Heat Irradiation Influence Real-time Spectrum Real Reaction Condition Heterogeneous Catalysis Aromatization Nano-sized Hzsm-5 Zeolite |
ISSN号 | 0253-9837 |
DOI | 10.1016/S1872-2067(17)62751-7 |
文献子类 | Article |
英文摘要 | An operando dual-beam Fourier transform infrared (DB-FTIR) spectrometer was successfully developed using a facile method. The DB-FTIR spectrometer is suitable for the real-time study of the dynamic surface processes involved in gas/solid heterogeneous catalysis under real reaction conditions because it can simultaneously collect reference and sample spectra. The influence of gas-phase molecular vibration and heat irradiation at real reaction temperatures can therefore be eliminated. The DB-FTIR spectrometer was successfully used to follow the transformation of isobutene over nano-sized HZSM-5 zeolite under real reaction conditions. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
WOS关键词 | FT-IR SPECTROSCOPY ; LOW-TEMPERATURE ; CO OXIDATION ; CATALYSTS ; MECHANISM ; METHANE ; ACID ; H-2 |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:000394481400003 |
出版者 | SCIENCE PRESS |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169562] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Guo, Hongchen |
作者单位 | 1.Dalian Univ Technol, Dept Catalyt Chem & Engn, Dalian 116012, Liaoning, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Xin, Qin,Liu, Jiaxu,Wang, Jilei,et al. Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(1):13-19. |
APA | Xin, Qin.,Liu, Jiaxu.,Wang, Jilei.,Zhou, Wei.,Miao, Cuilan.,...&Guo, Hongchen.(2017).Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite.CHINESE JOURNAL OF CATALYSIS,38(1),13-19. |
MLA | Xin, Qin,et al."Construction of an operando dual-beam fourier transform infrared spectrometer and its application in the observation of isobutene reactions over nano-sized HZSM-5 zeolite".CHINESE JOURNAL OF CATALYSIS 38.1(2017):13-19. |
入库方式: OAI收割
来源:大连化学物理研究所
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