Hydrothermal Carbon Enriched with Oxygenated Groups from Bio-mass Glucose as an Efficient Carbocatalyst
文献类型：期刊论文
| 作者 | Schloegl, Robert3; Wen, Guodong2; Wang, Bolun2; Wang, Congxin1; Wang, Jia2; Tian, Zhijian1; Su, Dang Sheng1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-01-09 |
| 卷号 | 56期号:2页码:600-604 |
| 关键词 | Beckmann Rearrangement Carbocatalysts Glucose Hydrothermal Reaction Nitrobenzene Reduction |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201609047 |
| 文献子类 | Article |
| 英文摘要 | Metal-free carbocatalysts enriched with specific oxygenated groups with different morphology and size were synthesized from glucose by hydrothermal carbonization, in which cheap and widely available biomass could be converted into functionalized carbon using an environmentally benign process. The hydroxy-and carbonyl-enriched hydrothermal carbon (HTC) could be used in nitrobenzene reduction, and higher conversion was obtained on the sphere morphology with smaller size. In the Beckmann rearrangement of cyclohexanone oxime, carboxyl-enriched HTC exhibited superior performance compared with conventional solid acid (such as HY and HZSM-5), on which the strong acid sites and weak Lewis acid sites lead to high selectivity for the side product. Although the intrinsic acidity of carbon is weak, the carboxyl-enriched carbon was used in weak Bronsted acid-catalyzed reactions, such as the Beckmann rearrangement. |
| WOS关键词 | PHASE BECKMANN REARRANGEMENT ; SELECTIVE AEROBIC OXIDATION ; LIQUID-PHASE ; CATALYTIC-ACTIVITY ; GRAPHENE OXIDE ; DEHYDROGENATION ; ACID ; REDUCTION ; NANOTUBES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000394996100028 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169570]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Su, Dang Sheng |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Peoples R China 3.Fritz Haber Inst Max Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany |
| 推荐引用方式 GB/T 7714 | Schloegl, Robert,Wen, Guodong,Wang, Bolun,et al. Hydrothermal Carbon Enriched with Oxygenated Groups from Bio-mass Glucose as an Efficient Carbocatalyst[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(2):600-604. |
| APA | Schloegl, Robert.,Wen, Guodong.,Wang, Bolun.,Wang, Congxin.,Wang, Jia.,...&Su, Dang Sheng.(2017).Hydrothermal Carbon Enriched with Oxygenated Groups from Bio-mass Glucose as an Efficient Carbocatalyst.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(2),600-604. |
| MLA | Schloegl, Robert,et al."Hydrothermal Carbon Enriched with Oxygenated Groups from Bio-mass Glucose as an Efficient Carbocatalyst".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.2(2017):600-604. |
入库方式： OAI收割
来源：大连化学物理研究所
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