ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene
文献类型：期刊论文
| 作者 | Zhang, Tao1; Tan, Yuan1,2; Liu, Xiao Yan1; Zhang, Leilei1; Wang, Aiqin1; Li, Lin1; Pan, Xiaoli1; Miao, Shu1; Haruta, Masatake1,3; Wei, Haisheng1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-03-01 |
| 卷号 | 56期号:10页码:2709-2713 |
| 关键词 | Gold Nanoclusters Hydrogenation 3-nitrostyrene Supported Catalysts Znal-hydrotalcite |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201610736 |
| 文献子类 | Article |
| 英文摘要 | Chemoselective hydrogenation of 3-nitrostyrene to 3-vinylaniline is quite challenging because of competitive activation of the vinyl group and the nitro group over most supported precious-metal catalysts. A precatalyst comprised of thiolated Au-25 nanoclusters supported on ZnAl-hydrotalcite yielded gold catalysts of a well-controlled size (ca. 2.0 nm)-even after calcination at 500 degrees C. The catalyst showed excellent selectivity (> 98%) with respect to 3-vinylaniline, and complete conversion of 3-nitrostyrene over broad reaction duration and temperature windows. This result is unprecedented for gold catalysts. In contrast to traditional catalysts, the gold catalyst is inert with respect to the vinyl group and is only active with regard to the nitro group, as demonstrated by the results of the control experiments and attenuated total reflection infrared spectra. The findings may extend to design of gold catalysts with excellent chemoselectivity for use in the synthesis of fine chemicals. |
| WOS关键词 | CO OXIDATION ; FUNCTIONALIZED NITROARENES ; GOLD CATALYSTS ; AU-25(SR)(18) NANOCLUSTERS ; SUBSTITUTED NITROAROMATICS ; PLATINUM NANOPARTICLES ; ATOMIC PRECISION ; REDUCTION ; SIZE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000395183600028 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169614]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Tao; Liu, Xiao Yan |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, iChEM,Gold Catalysis Res Ctr, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tokyo Metropolitan Univ, Dept Appl Chem, Hachioji, Tokyo 1920397, Japan |
| 推荐引用方式 GB/T 7714 | Zhang, Tao,Tan, Yuan,Liu, Xiao Yan,et al. ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(10):2709-2713. |
| APA | Zhang, Tao.,Tan, Yuan.,Liu, Xiao Yan.,Zhang, Leilei.,Wang, Aiqin.,...&Wang, Xiaodong.(2017).ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(10),2709-2713. |
| MLA | Zhang, Tao,et al."ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.10(2017):2709-2713. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。