Functions in cooperation for enhanced oxygen reduction reaction: the independent roles of oxygen and nitrogen sites in metal-free nanocarbon and their functional synergy
文献类型：期刊论文
| 作者 | Gentle, Ian R.2; Wu, Kuang-Hsu1,2; Wang, Da-Wei3; Zong, Xu4; Zhang, Bingsen1; Liu, Yuefeng5; Su, Dang-Sheng1,5 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2017 |
| 卷号 | 5期号:7页码:3239-3248 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c6ta10336g |
| 文献子类 | Article |
| 英文摘要 | Heteroatom-doped nanocarbons are known to behave differently in the oxygen reduction reaction (ORR) in aqueous systems. In the present study, we reveal the dissimilar roles of oxygen and nitrogen sites in nanocarbons and show that the different functions can jointly promote the ORR in cooperation when appropriately combined. The oxygen sites in general could efficiently facilitate both the HO2- generation and the reduction at high overpotential, while the active nitrogen sites could activate the ORR with a lower energy requirement and simultaneously reduce both O-2 and HO2- at low overpotential. A further study to integrate the functionalities in a single nanocarbon reveals the oxidation-resistant nature of the active nitrogen functional group, a chemical basis for the reactivity. |
| WOS关键词 | DOPED CARBON NANOTUBES ; FREE ELECTROCATALYSTS ; GRAPHENE OXIDE ; ACTIVE-SITES ; CATALYSTS ; ELECTROREDUCTION ; SPECTRA |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000395077600021 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169616]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wang, Da-Wei; Su, Dang-Sheng |
| 作者单位 | 1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld 4072, Australia 3.Univ New South Wales, Sch Chem Engn, Sydney, NSW 2052, Australia 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 5.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gentle, Ian R.,Wu, Kuang-Hsu,Wang, Da-Wei,et al. Functions in cooperation for enhanced oxygen reduction reaction: the independent roles of oxygen and nitrogen sites in metal-free nanocarbon and their functional synergy[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(7):3239-3248. |
| APA | Gentle, Ian R..,Wu, Kuang-Hsu.,Wang, Da-Wei.,Zong, Xu.,Zhang, Bingsen.,...&Su, Dang-Sheng.(2017).Functions in cooperation for enhanced oxygen reduction reaction: the independent roles of oxygen and nitrogen sites in metal-free nanocarbon and their functional synergy.JOURNAL OF MATERIALS CHEMISTRY A,5(7),3239-3248. |
| MLA | Gentle, Ian R.,et al."Functions in cooperation for enhanced oxygen reduction reaction: the independent roles of oxygen and nitrogen sites in metal-free nanocarbon and their functional synergy".JOURNAL OF MATERIALS CHEMISTRY A 5.7(2017):3239-3248. |
入库方式： OAI收割
来源：大连化学物理研究所
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