A Critical Review on the Catalytic Applications of Non-Metallic Gold Nanoclusters: Selective Oxidation, Hydrogenation, and Coupling Reactions
文献类型：期刊论文
| 作者 | Li, Gao1; Li, Zhimin1,3; Abroshan, Hadi2; Liu, Chao1 |
| 刊名 | CURRENT ORGANIC CHEMISTRY
 |
| 出版日期 | 2017 |
| 卷号 | 21期号:6页码:476-488 |
| 关键词 | Gold Nanocluster Oxidation Hydrogenation C-c Coupling Dft Size-specificity Ligand Effects Doping Effects |
| ISSN号 | 1385-2728 |
| DOI | 10.2174/1385272820666161020152707 |
| 文献子类 | Review |
| 英文摘要 | In recent decade, gold nanoclusters with atomic precision (AunLm where L = ligand) have been demonstrated as a new and promising class of nanocatalysts. The AunLm catalysts of different sizes possess unique crystal and electronic structures, thereby providing an excellent opportunity to correlate the intrinsic catalytic performance with the catalysts' structure as well as to study mechanisms of chemical reactions catalyzed over gold nanoparticles. In this review, controlled synthesis of atomically precise gold nanoclusters and their thermal stabilities are explained. We demonstrate important roles played by the gold nanoclusters for catalytic reactions, including selective oxidation and hydrogenation as well as carbon-carbon coupling reactions. Tailoring of the catalysts' functions is discussed in terms of size-specificity, ligand engineering (e. g., aromatic vs aliphatic), and doping effects (e. g., copper, silver, palladium, and platinum). The proposed reactions' mechanisms and the structureactivity relationships at the atomic detail are presented. |
| WOS关键词 | CHEMOSELECTIVE HYDROGENATION ; CO OXIDATION ; AU-25 NANOCLUSTERS ; AU-25(SCH2CH2PH)(18) NANOCLUSTERS ; OPTICAL-PROPERTIES ; ACTIVE-SITE ; CLUSTERS ; NANOPARTICLES ; SIZE ; SEMIHYDROGENATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000394172900001 |
| 出版者 | BENTHAM SCIENCE PUBL LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/169626]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Gao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China 2.Carnegie Mellon Univ, Dept Chem, 4400 5th Ave, Pittsburgh, PA 15213 USA 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Gao,Li, Zhimin,Abroshan, Hadi,et al. A Critical Review on the Catalytic Applications of Non-Metallic Gold Nanoclusters: Selective Oxidation, Hydrogenation, and Coupling Reactions[J]. CURRENT ORGANIC CHEMISTRY,2017,21(6):476-488. |
| APA | Li, Gao,Li, Zhimin,Abroshan, Hadi,&Liu, Chao.(2017).A Critical Review on the Catalytic Applications of Non-Metallic Gold Nanoclusters: Selective Oxidation, Hydrogenation, and Coupling Reactions.CURRENT ORGANIC CHEMISTRY,21(6),476-488. |
| MLA | Li, Gao,et al."A Critical Review on the Catalytic Applications of Non-Metallic Gold Nanoclusters: Selective Oxidation, Hydrogenation, and Coupling Reactions".CURRENT ORGANIC CHEMISTRY 21.6(2017):476-488. |
入库方式： OAI收割
来源：大连化学物理研究所
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